# US 7,408,087 B2 · Process for making unsaturated coconut and/or palm nut fatty alcohols

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- Number: US 7,408,087 B2
- Document ID: US7408087B2
- Status: Granted
- Kind: B2
- Application number: 09/874,899
- Filed: 2001-06-05
- Published: 2002-03-21
- Granted: 2008-08-05
- Earliest claimed: 2001-06-05
- Assignees: Cognis Deutschland GmbH & Co. KG
- Inventors: Stephan Heck; Norbert Klein; Horst-Dieter Komp; Christiane Boehr; Norbert Huebner; Alfred Westfechtel
- Web page: https://patentgrep.com/patent/US7408087B2

## CPC

- C07C 29/149: with hydrogen or hydrogen-containing gases
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS

## Abstract

Unsaturated coconut and/or palm nut fatty alcohols having an iodine number in the range from 65 to 85, which essentially comprise unsaturated fatty alcohols and mixtures of saturated fatty alcohols of the formula (I): R1OH (I) in which R1 is a saturated or unsaturated, linear or branched alkyl radical having 12 to 20 carbon atoms, obtainable by fractionating coconut and/or palm nut fatty acid methyl esters to obtain a fraction containing predominantly C16-C18 portions, fractionating the C16-C18 fatty acid methyl ester fraction into a predominantly saturated distillate and a predominantly unsaturated bottom product, and hydrogenating the bottom product with retention of the double bonds to give the corresponding alcohols; are disclosed.

## Claims

### Claim 1

A process for the preparation of a mixture of fatty alcohols having an iodine number in the range from 65 to 85 of the formula (I)
R1OH (I)
wherein R1 is a saturated or unsaturated, linear or branched radical having from 14 to 20 carbon atoms, wherein the process comprises the steps of:
(a) fractionating coconut and/or palm nut fatty acid methyl esters to produce a methyl ester fraction comprised substantially of C18-C18 portions,
(b) fractionating the C16-C18 fatty acid methyl ester fraction of step (a) to produce a distillate comprised of predominantly saturated methyl esters and a bottom fraction comprised of substantially unsaturated methyl esters,
(c) hydrogenating the bottom fraction to give the corresponding alcohols under conditions such that the carbon-carbon double bonds remain intact.

### Claim 2 (depends on 1)

The process of claim 1 wherein the fractionating step of (a) is carried out batchwise or continuously.

### Claim 3 (depends on 1)

The process of claim 1 wherein the fractionation step of (a) is carried out at a pressure of from 1 to 20 mbar.

### Claim 4 (depends on 1)

The process of claim 1 wherein the fractionation step of (b) is carried out at a pressure of from 5 to 10 mbar.

### Claim 5 (depends on 1)

The process of claim 1 wherein the distillate and the bottom fraction of step (b) are present in a weight ratio of from 10:90 to 5:85.