# US 7,407,926 B2 · Oil-containing surfactant gels comprising a mixture of ethoxylated citric acid esters

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- Number: US 7,407,926 B2
- Document ID: US7407926B2
- Status: Granted
- Kind: B2
- Application number: 11/263,009
- Filed: 2005-10-31
- Published: 2006-05-18
- Granted: 2008-08-05
- Earliest claimed: 2004-11-12
- Assignees: Cognis IP Management GmbH
- Inventors: Michael Mueller
- Web page: https://patentgrep.com/patent/US7407926B2

## CPC

- A61K 8/042: {Gels}
- A61K 8/22: Peroxides; Oxygen; Ozone
- A61K 8/39: Derivatives containing from 2 to 10 oxyalkylene groups
- A61K 8/86: Polyethers
- A61K 8/92: Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61Q 19/00: Preparations for care of the skin
- A61Q 5/00: Preparations for care of the hair
- A61K: PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES (devices or methods specially adapted for bringing pharmaceutical products into particular physical or administering forms A61J3/00; chemical aspects of, or use of materials for deodorisation of air, for disinfection or sterilisation, or for bandages, dressings, absorbent pads or surgical articles A61L; soap compositions C11D)
- A61Q: SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS

## Abstract

The invention relates to gel-form cosmetic preparations containing (a) 5 to 50% by weight of surfactants; (b) 5 to 50% by weight of oils and/or waxes; (c) 0 to 15% by weight of water-soluble polyols; and component (a) contains at least 10% by weight, based on component (a) as a whole, of a mixture of citric acid esters of alkoxylated alcohols and the sum of components (a) and (b) in the preparation as a whole being from 10 to 70% by weight.

## Claims

### Claim 1

A gel-form cosmetic preparation comprising:
(a) 5 to 50% by weight of surfactants;
(b) 5 to 50% by weight of oils and/or waxes;
(c) 0 to 15% by weight of water-soluble polyols;
wherein, component (a) contains at least 10% by weight, based on component (a) as a whole, of a mixture of citric acid esters of alkoxylated alcohols of the formula R1O(CH2CH2O)nH, wherein, R1 is a linear or branched alkyl or alkenyl group containing 4 to 24 carbon atoms, and n is a number of from 1 to 50 and a sum of components (a) and (b) in the preparation as a whole being from 10 to 70% by weight, and with the proviso that the ratio by weight of monoester to diester in the citric acid ester mixture is in a range of 3:1 to 10:1.

### Claim 2 (depends on 1)

The preparation as claimed in claim 1, wherein, in addition to the citric acid esters of alkoxylated alcohols, component (a) contains at least one co-surfactant selected from the group consisting of anionic, cationic, non ionic, amphoteric and zwitterionic surfactants.

### Claim 3 (depends on 2)

The preparation as claimed in claim 2, wherein, component (a) contains at least one co-surfactant selected from the group consisting of betaines, acylated amino acids, alkyl ether sulfates, alkyl sulfates and alkyl oligoglycosides.

### Claim 4 (depends on 1)

The preparation as claimed in claim 1, wherein, component (a) comprises a mixture of esters of citric acid of ethoxylated alcohols of the formula:
R1O(CH2CH2O)nH (I)
in which R1 is a linear alkyl group containing 4 to 24 carbon atoms and n is a number of 5 to 9.

### Claim 5 (depends on 1)

The preparation of claim 1, wherein, component (c) comprises at least one member selected from the group consisting of glycerol, ethylene glycol and propylene glycol.

### Claim 6 (depends on 1)

The preparation of claim 1, wherein, the preparation additionally contains hydrogen peroxide.

### Claim 7 (depends on 1)

The preparation of claim 1, wherein, the preparation additionally contains water.

### Claim 8 (depends on 2)

The preparation of claim 2, wherein, component (a) comprises a mixture of esters of citric acid of ethoxylated alcohols of the formula:
R1O(CH2CH2O)nH (I)
in which R1 is a linear or branched alkyl or alkenyl group containing 4 to 24 carbon atoms and n is a number of 1 to 20.

### Claim 9 (depends on 8)

The preparation of claim 8, wherein, component (c) comprises at least one member selected from the group consisting of glycerol, ethylene glycol and propylene glycol.

### Claim 10 (depends on 9)

The preparation of claim 9, wherein, the preparation additionally contains hydrogen peroxide.

### Claim 11 (depends on 8)

The preparation of claim 8, wherein, the preparation additionally contains water.

### Claim 12 (depends on 3)

The preparation of claim 3, wherein, component (a) comprises a mixture of esters of citric acid of ethoxylated alcohols of the formula:
R1O(CH2CH2O)nH (I)
in which R1 is a linear or branched alkyl or alkenyl group containing 4 to 24 carbon atoms and n is a number of 1 to 10.

### Claim 13 (depends on 12)

The preparation of claim 12, wherein, component (c) comprises at least one member selected from the group consisting of glycerol, ethylene glycol and propylene glycol.

### Claim 14 (depends on 13)

The preparation of claim 13, wherein, the preparation additionally contains hydrogen peroxide.

### Claim 15 (depends on 12)

The preparation of claim 12, wherein, the preparation additionally contains water.

### Claim 16 (depends on 4)

The preparation of claim 4, wherein, component (c) comprises at least one member selected from the group consisting of glycerol, ethylene glycol and propylene glycol.

### Claim 17 (depends on 4)

The preparation of claim 4, wherein, the preparation additionally contains hydrogen peroxide.

### Claim 18 (depends on 4)

The preparation of claim 4, wherein, the preparation additionally contains water.

### Claim 19 (depends on 5)

The preparation of claim 5, wherein, the preparation additionally contains water.
