Soluble polyfunctional vinyl aromatic polymer and method of producing the same
AssigneeNippon Steel Chemical Co., Ltd.
InventorMasanao Kawabe
Life of this patent
Estimating the term…
Loading patent…
AssigneeNippon Steel Chemical Co., Ltd.
InventorMasanao Kawabe
Estimating the term…
The present invention relates to a soluble polyfunctional vinylaromatic copolymer improved in heat resistance, resistance to thermal decomposition, solvent solubility, and processability. The soluble polyfunctional vinylaromatic polymer is obtained by cationically polymerizing, at a temperature of 20 to 120° C., one or more monomer ingredients including 20 to 100 mol % divinylaromatic compound (a) in the presence of a donor ingredient, e.g., a quaternary ammonium salt, with the aid of a Lewis acid catalyst and an initiator represented by the following general formula (1) wherein R1 represents hydrogen or a monovalent C1-6 hydrocarbon group; R2 represents an aromatic or aliphatic hydrocarbon group having a valence of p; Z represents halogen or C1-6 alkoxy or acyloxy; and p is an integer of 1 to 6; provided that when two or more R1's and Z's are present per molecule, they may be identical to different from each other.
A method of producing a soluble polyfunctional vinyl aromatic polymer having a controlled molecular weight distribution, comprising performing cationic polymerization of a monomer component containing 20 to 100 mol % of a divinyl aromatic compound (a) at a temperature of 20 to 120° C. in an organic solvent in the presence of a donor component selected from the group consisting of a quaternary ammonium salt, an ether-based compound having 3 or more carbon atoms, a thioether-based compound having 3 or more carbon atoms, and a sulfoxide-based compound having 2 or more carbon atoms with a Lewis acid catalyst and an initiator represented by the following general formula (1):
A method of producing a soluble polyfunctional vinyl aromatic polymer having a controlled molecular weight distribution, comprising performing cationic polymerization of a monomer component containing 20 to 100 mol % of a divinyl aromatic compound (a) at a temperature of 20to 120° C. in at least one organic solvent having a dielectric constant of 2 to 15 with a Lewis acid catalyst and an initiator represented by the following general formula (1):
A soluble polyfunctional vinyl aromatic copolymer comprising an indan structure represented by the following general formula (2) in a main chain skeleton:
Dependencies are inferred from the claim text.