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US 7,402,343 B2Granted
Molecular chemical compounds with structures allowing electron displacement and capable of emitting photoluminescent radiation, and photoluminescence quenching device employing the same
AssigneeSamsung SDI Co., Ltd.
InventorMichael Redecker
Life of this patent
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Abstract
A chemical compound which has an electron donor group, an electron acceptor group, and a conjugated bridging element bridging between the electron donor group and the electron acceptor group. The chemical compound has a readily displaceable electron, is capable of emitting photoluminescent radiation. A dipole character is present therein only in the excited state of the compound. The compounds are suitable for use in optical devices and, particularly, can be used for photoluminescence quenching devices.
Claims14
A photoluminescence quenching device comprising a chemical compound, comprising:
- an electron donor group at one end of the chemical compound, the electron donor group is selected from the group consisting of carbazole, thiophene, compounds of formulas 1a through 1d, thiophene, and oligomers thereof:
- an electron acceptor group at the other end of the chemical compound, the electron acceptor group selected from the group consisting of monosubstituted phenyl, disubstituted phenyl, trisubstituted phenyl, imide and anhydride of aromatic polycarboxylic acid, oxazole, a fused cyclic system, a compound having a chemical basic structure selected from the group consisting of a fluorine-substituted phenyl group, a nitro-substituted phenyl group, a cyano-substituted phenyl group, imide and anhydride of perylenetetracarboxylic acid and a substituted compound thereof, imide and anhydride of naphthalenetetracarboxylic acid and a substituted compound thereof, oxadiazole and a substituted compound thereof, oxazole and a substituted compound thereof, and a fluorenylidene moiety and a substituted compound thereof, and the following compounds of formulas 3a through 3m;
- a conjugated bridging element, said electron donor group and said electron acceptor group linked to each other via said conjugated bridging element,
- wherein said chemical compound has a readily displaceable electron, a dipole character is present only in the excited state, and said chemical compound is capable of emitting photoluminescent radiation, and the photoluminescent quenching device generates photoluminescent light by using exterior light and is capable of auto-emitting photoluminescent light when light is sparse or absent.
1 more element
A photoluminescence quenching device, comprising:
- a glass substrate;
- a layer of conductive transparent indium-tin oxide (ITO) on said glass substrate;
- a layer of poly(ethylenedioxythiophene)/polystyrenesulfonic acid conductive polymer with a layer thickness of from 30 to 100 nm on said layer of conductive transparent indium-tin-oxide;
- an emitter polymer layer having a thickness of from 50 to 150 nm, said emitter polymer layer having a material selected from the group consisting of the following compounds of formula 5a through 5c:
- wherein n is a number ranging from 100 to 2,000,
- wherein n is a number ranging from 100 to 2,000, and
- wherein n is a number ranging from 100 to 2,000;
- a metal contact;
- and
- an aluminum layer with a layer thickness of from 50 to 200 nm.
7 more elements
A photoluminescence quenching device, comprising:
- two metal films;
- and
- a chemical layer embedded between the two metal films, the chemical layer comprised of a compound having:
- an electron donor group at one end of the compound, the electron donor group is selected from the group consisting of carbazole, thiophene, compounds of formulas 1a through 1d, thiophene, and oligomers thereof:
- an electron acceptor group at the other end of the compound, the electron acceptor group selected from the group consisting of monosubstituted phenyl, disubstituted phenyl, trisubstituted phenyl, imide and anhydride of aromatic polycarboxylic acid, oxazole, a fused cyclic system, a compound having a chemical basic structure selected from the group consisting of a fluorine-substituted phenyl group, a nitro-substituted phenyl group, a cyano-substituted phenyl group, imide and anhydride of perylenetetracarboxylic acid and a substituted compound thereof, imide and anhydride of naphthalenetetracarboxylic acid and a substituted compound thereof, oxadiazole and a substituted compound thereof, oxazole and a substituted compound thereof, and a fluorenylidene moiety and a substituted compound thereof, and the following compounds of formulas 3a through 3m:
- a conjugated bridging element, said electron donor group and said electron acceptor group linked to each other via said conjugated bridging element,
- said compound having a readily displaceable electron, a dipole character being present only in the excited state, said compound being capable of emitting photoluminescent radiation,
- wherein the photoluminescent quenching device generates photoluminescent light by using exterior light and is capable of auto-emitting photoluminescent light when light is sparse or absent.
5 more elements
A compound, selected from the group consisting of the following compounds of formulas 4a through 4c:
A compound, selected from the group consisting of the following compounds of formula 5a through 5c:
- wherein n is a number ranging from 100 to 2,000,
- wherein n is a number ranging from 100 to 2,000, and
- wherein n is a number ranging from 100 to 2,000.
Dependencies are inferred from the claim text.