Process and apparatus for alkylation of aromatic with olefin using impure aromatic recycle
AssigneeUop LLC
InventorsStephen W. Sohn, Michael R. Smith, Lance A. Baird
Life of this patent
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Abstract
Processes and apparatus for the alkylation of aromatic compound with mono-olefin aliphatic compound in the presence of solid alkylation catalyst use a lights distillation for obtaining desired selectivities to arylalkane in a energy efficient manner. The processes and apparatus offer the potential for debottlenecking existing arylalkane production facilities and reducing the size and energy requirements for a new arylalkane production facility.
Claims14
A process for the alkylation of aromatic compound having from 6 to 8 carbon atoms per molecule with an olefin-containing aliphatic compound having from 8 to 18 carbon atoms per molecule, the process comprising:
- a. co-currently passing the aromatic compound, the olefin-containing aliphatic compound, and a paraffin having from 8 to 18 carbon atoms per molecule to an alkylation zone containing solid alkylation catalyst and operating under alkylation conditions to produce an effluent comprising an arylalkane, the aromatic compound, and the paraffin, wherein the alkylation conditions comprise a liquid phase, a molar ratio of the aromatic compound passed to the alkylation zone to the olefin-containing aliphatic compound passed to the alkylation zone of at least about 6:1 and a molar ratio of the paraffin passed to the alkylation zone to the olefin-containing aliphatic compound passed to the alkylation zone of about 1:1 to 20:1;
- b. distilling a first distillation feed comprising at least a portion of the effluent, said distillation being conducted with less than about 5 theoretical distillation plates, at a distillation pressure of less than about 500 kPa absolute, and with less than about 40 kcal of heat being externally supplied per kilogram of the first distillation feed so as to provide a first overhead comprising between about 20 and 98 weight percent of the aromatic compound contained in the at least a portion of the effluent and arylalkane, and a first bottoms stream comprising the aromatic compound and at least about 80 weight percent of the arylalkane contained in the at least a portion of the effluent;
- c. recycling at least a portion of the first overhead to the alkylation zone;
- and
- d. distilling a second distillation feed comprising at least a portion of the first bottoms stream under distillation conditions sufficient to provide a second overhead comprising the aromatic compound and a second bottoms stream comprising the arylalkane and having an essential absence of the aromatic compound.
A process for the alkylation of an aromatic compound having from 6 to 8 carbon atoms per molecule with an olefin-containing aliphatic compound having from 8 to 18 carbon atoms per molecule, the process comprising:
- a. co-currently passing the aromatic compound, the olefin-containing aliphatic compound and a paraffin having from 8 to 18 carbon atoms per molecule to an alkylation zone containing solid alkylation catalyst and operating under alkylation conditions to produce an effluent comprising an arylalkane, the aromatic compound, and the paraffin, wherein the alkylation conditions comprise a liquid phase, a molar ratio of the aromatic compound passed to the alkylation zone to the olefin-containing aliphatic compound passed to the alkylation zone of at least about 6:1 and a molar ratio of the paraffin passed to the alkylation zone to the olefin-containing aliphatic compound passed to the alkylation zone of between about 1:1 to 20:1;
- b. distilling a first distillation feed comprising at least a portion of the effluent, said distillation being conducted with less than about 5 theoretical distillation plates to provide a first overhead comprising between about 20 and 98 weight percent of the aromatic compound contained in the at least a portion of the effluent and arylalkane, and a first bottoms stream comprising the aromatic compound and at least about 80 weight percent of the arylalkane contained in the at least a portion of the effluent;
- c. recycling at least a portion of the first overhead to the alkylation zone;
- d. distilling a second distillation feed comprising at least a portion of the first bottoms stream under distillation conditions sufficient to provide a second overhead comprising the aromatic compound and a second bottoms stream comprising the arylalkane and having an essential absence of the aromatic compound;
- and
- e. withdrawing from at least one of steps a, b and c, sufficient fluid to maintain a concentration of the paraffin in the effluent at less than about 50 weight percent and passing at least a portion of the fluid withdrawn from at least one of steps a, b, and c to said distilling of step d.
Dependencies are inferred from the claim text.