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US 7,396,638 B2Granted
Photothermographic material and image forming method
AssigneeFUJIFILM Corporation
InventorFumito Nariyuki
Life of this patent
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Abstract
The present invention relates to a photothermographic material including, on a same surface of a support, a photosensitive silver halide, a non-photosensitive organic silver salt, a reducing agent and a binder, wherein the photosensitive silver halide has a silver iodide content within a range from 40 to 100 mol %, and the material is thermally developed within a developing time of 12 seconds or less. The invention also relates to an image forming method using the photothermographic material.
Claims15
An image forming method comprising:
- image-wise exposing to a blue semiconductor laser which has a light emission peak intensity within a wavelength range of 350 to 450 nm a photothermographic material comprising, on a same surface of a support, a photosensitive silver halide having a silver iodide content of 40 to 100 mol %, a non-photosensitive organic silver salt of an aliphatic carboxylic acid including a silver behenate, a reducing agent, a binder, and an adsorbable redox compound represented by Formula (I), wherein, in Formula (I), A represents a group that can be adsorbed by silver halide;
- W represents a divalent connecting group;
- n represents 0 or 1;
- B represents a reducing group that is capable of reducing silver ions and is a residue derived from a compound represented Formula B13;
- and
- thermally developing the image-wise exposed photothermographic material with a developing time of 1 to 12 seconds and with a developing temperature of 110° C. to 140° C.;
- wherein in Formula B13, Rb13, represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group;
- RH13 represents a hydrogen atom, an alkyl group, an aryl group, an acyl group, an alkylsulfonyl group or an arylsulfonyl group;
- Rb130 to Rb133 each independently represent a hydrogen atom or a substituent;
- A-(W)n—B Formula (1)
- wherein the photothermographic material further includes a compound represented by the following formula (H):
- Q-(Y)n—C(Z1)(Z2)X Formula (H)
- wherein in formula (H), Q represents an alkyl group, an aryl group or a heterocyclic group;
- Y represents a divalent connecting group;
- n represents 0 or 1;
- Z1 and Z2 each independently represent a halogen atom;
- and X represents a hydrogen atom or an electron attracting group
- and wherein the reducing agent is a compound represented by the following formula (R-1):
- wherein in formula (R-1), R11 and R11′ each independently represent an alkyl group having 1 to 20 carbon atoms;
- R12 and R12′ each independently represent an alkyl group having 2 to 20 carbon atoms;
- L represents a —S—group or a —CHR13— group;
- R13 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms;
- X1 and X1′ each independently represent a hydrogen atom or a group that can substitute a benzene ring.
20 more elements
Dependencies are inferred from the claim text.