Method of producing translucent ceramic
AssigneeMurata Manufacturing Co., Ltd.
InventorsNobuhiko Tanaka, Yukio Higuchi, Masayoshi Katsube, Mitsuru Sube
Life of this patent
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Abstract
A ceramic material powder for a translucent ceramic is molded with a binder, and the resulting green compact is embedded in a ceramic powder having the same composition with the ceramic material powder. After removing the binder, the green compact embedded in the ceramic powder is fired in an atmosphere having an oxygen concentration higher than that in the removal procedure of the binder and thereby yields a translucent ceramic represented by Formula I: Ba{(SnuZr1-u)xMgyTaz}vOw, Formula II: Ba(ZrxMgyTaz)vOw or Formula III: Ba{(SnuZr1-u)x(ZntMg1-t)yNbz}vOw. The translucent ceramic has a refractive index of 1.9 or more and is paraelectric.
Claims16
A method of producing a translucent ceramic having a refractive index of equal to or more than 1.9 and being paraelectric and comprising a polycrystalline oxide perovskite crystal phase, the method comprising the steps of:
- molding a ceramic material powder and a binder into a predetermined shape to thereby yield a translucent ceramic green compact comprising a perovskite crystal phase represented by the formula ABO3 wherein A is an A-site element comprising Ba in the perovskite crystal phase;
- and B is a B-site element and is two of Mg, Ta, Nb, Zn and Ta in the perovskite crystal phase,
- bringing the ceramic green compact into contact with a ceramic powder having substantially the same composition with the ceramic material powder, and
- firing the ceramic green compact in contact with the ceramic powder to thereby yield said translucent ceramic,
- wherein the perovskite crystal phase is a member of the group consisting of
- (a) Formula I:
- Ba{(SnuZr1-u)xMgyTaz}vOw in which x+y+z=1, 0≦u≦1.00, 1.00≦v≦1.05;
- w is arbitrary;
- and x, y, and z lie within the range enclosed by Point A (x=0.40, y=0.23, z=0.37), Point B (x=0, y=0.39, z=0.61), Point C (x=0, y=0.27, z=0.73), and Point D (x=0.40, y=0.11, z=0.49), excluding the line between Point A and Point B,
- (b) Formula II:
- Ba(ZrxZnyTaz)vOw in which x+y+z=1, 1.00≦v≦1.050;
- w is arbitrary;
- and x, y, and z in Formula I lie within the range enclosed by Point A (x=0.01, y=0.29, z=0.70), Point B (x=0.06, y=0.29, z=0.65), Point C (x=0.06, y=0.36, z=0.58), and Point D (x=0.01, y=0.36, z=0.63), and
- (c) Formula III:
- Ba{(SnuZr1-u)x(ZntMg1-t)yNbz}vOw in which x+y+z=1, 0≦t≦1.00, 0≦u≦1.00, 1.00≦v≦1.450;
- w is arbitrary;
- and x, y, and z lie within the range enclosed by Point A (x=0.25, y=0.35, z=0.40), Point B (x=0, y=0.35, z=0.65), Point C (x=0, y=0.20, z=0.80), Point D (x=0.10, y=0.10, z=0.80), Point E (x=0.55, y=0.10, z=0.35), Point F (x=0.35, y=0.30, z=0.35), and Point G (x=0.30, y=0.30, z=0.40).
Dependencies are inferred from the claim text.