Silver salt photothermographic dry imaging material, image recording method and image forming method for the same
AssigneeKonica Minolta Holdings, Inc.
InventorsHiroshi Kashiwagi, Narito Goto
Life of this patent
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Abstract
A silver salt photothermographic dry imaging material including non-photosensitive aliphatic carboxylic acid silver salts; a photosensitive emulsion containing photosensitive silver halide grains; a silver ion reducing agent; a binder; and a cyan coloring leuco dye. A percentage of the photosensitive silver halide grains having a mean particle size of 0.01 or more μm and 0.04 μm or less is 5% or more by mass and 50% or less by mass of total photosensitive silver halide grains by conversion into a silver amount.
Claims25
A silver salt photothermographic dry imaging material comprising:
- a support;
- a photosensitive layer containing non-photosensitive aliphatic carboxylic acid silver salts, photosensitive silver halide grains, a silver ion reducing agent and a binder, the photosensitive layer being provided on the support;
- a cyan coloring leuco dye;
- and
- at least one compound selected from the group of compounds represented by the following Formulas (1) to (4), (A-8), (A-9), (PO) and (J),
- wherein in the Formula (1), each of the X01 and X02 represents a hydrogen atom, a halogen atom, an alkyl group, a cycloalkyl group, an aryl group, a heterocyclic group, a —COOH or a salt thereof, or an aryl group or alkyl group which is bonded via a bivalent linkage group, at least one of the X01 and X02 being —COOH or a salt thereof;
- and each of the R1, R2 and R3 represents a hydrogen atom, a halogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an aryl group, a heterocyclic group, or an aryl group or alkyl group which is bonded via a bivalent linkage group;
- in the Formula (2), the P represents an oxygen atom, a sulfur atom or an NH group;
- the Q1 represents an oxygen atom or a sulfur atom;
- the Y1 represents an OH group, an OM1 group, an SH group, an SM1 group or an NH2 group, the M1 representing a counter ion;
- the L1 represents a bivalent linkage group;
- and the Z10 represents an alkyl group, an aryl group or a heterocyclic group;
- in the Formula (3), the Z20 represents an aliphatic hydrocarbon group, an aryl group or a heterocyclic group;
- and the M2 represents a metal atom or an organic cation;
- in the Formula (4), the R4 represents a hydroxyl group or a metallic salt of the hydroxyl group;
- the R5 represents an alkyl group or an aryl group;
- and the X3 represents an electron withdrawing group, or the R5 and the X3 are capable of forming a ring including an electron withdrawing group;
- in the Formula (A-8), the Z80 represents an atomic group required for forming a nitrogen-containing heterocycle;
- the X80 represents an SO2 group or an OSO2 group;
- and the R80 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an alkaryl group, an aralkyl group or a heterocyclic group;
- in the Formula (A-9), the R91 represents a hydroxyl group or a metallic salt of the hydroxyl group;
- the R92 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an alkaryl group, an aralkyl group or a heterocyclic group;
- and each of the X91 and X92 represents an electron withdrawing group;
- in the Formula (PO), each of the Z03 and Z04 independently represents a halogen atom;
- the X10 represents a hydrogen atom or an electron withdrawing group;
- the Y01 represents a —CO— group or an SO2— group;
- the Q10 represents an arylene group or a bivalent heterocyclic group;
- the L3 represents a linkage group;
- each of the W1 and W2 independently represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group;
- and the n3 represents 0 or 1;
- and
- in the Formula (J), the R5 represents a monovalent substituent except a hydrogen atom;
- the m2 represents an integer of 1 to 6;
- and the (R5)m2 indicates that 1 to 6 R5s are independently exist on a phthalazine ring.
A silver salt photothermographic dry imaging material comprising:
- non-photosensitive aliphatic carboxylic acid silver salts;
- a photosensitive emulsion containing photosensitive silver halide grains;
- a silver ion reducing agent;
- a binder;
- and
- a cyan coloring leuco dye,
- wherein the binder contains latex of polymer with an equilibrium water content of 2% or less by mass at 25° C. and at 60% RH, wherein coefficient of determination R2 of a linear regression straight line is 0.998 or more and 1.000 or less, the R2 being made by measuring each density at optical density of 0.5, 1.0, 1.5 and minimum optical density on a silver image obtained after thermal development processing of the silver salt photothermographic dry imaging material and by disposing u* and v* at the above each optical density on two dimensional coordinates where a horizontal and vertical axes in CIE 1976 (L*u*v*) color space are made u* and v*, respectively;
- and v* value of an intersection point with the vertical axis of the linear regression straight line is −5 or more and 5 or less;
- and a slope (v*/u*) is 0.7 or more and 2.5 or less.
Dependencies are inferred from the claim text.