A component through which a hydrocarbon fluid flows at a temperature of about 315 to about 425° C., the component comprising a wall and a coating system on a first surface of the wall, the coating system comprising an outermost layer consisting of platinum and a ceramic barrier layer between the outermost layer and the wall, the hydrocarbon fluid contacting and flowing across the outermost layer, the platinum of the outermost layer catalyzing the hydrocarbon fluid to form particles of carbonaceous gum substances suspended within the hydrocarbon fluid, the ceramic barrier layer having a thickness sufficient to inhibit interdiffusion between the outermost layer and the wall, wherein the outermost layer has a thickness of a monolayer up to about 40 nm or the coating system has a thickness of up to about 100 nm.