Method for the production of hydrocyanic acid by oxidation of nitrogen-containing hydrocarbons in a flame
AssigneeBASF SE
InventorsKai Rainer Ehrhardt, Mayke Mueller-Eversbusch, Dieter Stapf
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AssigneeBASF SE
InventorsKai Rainer Ehrhardt, Mayke Mueller-Eversbusch, Dieter Stapf
Estimating the term…
A process is described for preparing hydrogen cyanide by autothermal noncatalytic oxidation of one or more nitrogenous hydrocarbons or a nitrogenous hydrocarbon mixture in which the nitrogenous hydrocarbons, an oxygen-containing gas, with or without ammonia, with or without water, with or without a gas containing nitrogen oxides and with or without other essentially inert feed gas constituents are introduced into a flame reaction zone, react in the flame reaction zone and a post-reaction zone at a temperature of from 1000 to 1800° C. for a reaction time of 0.03 to 0.3 s to form a cleavage gas which comprises at least the constituents hydrogen cyanide, carbon oxides, hydrogen, water, ammonia, nitrogen, light hydrocarbons with or without other cleavage gas constituents, the atomic C/N ratio in the reaction zones being from 1 to 7 and the atomic air ratio λato being <0.6, the cleavage gas being cooled and separated.
A process for preparing hydrogen cyanide by autothermal noncatalytic oxidation of one or more nitrogenous hydrocarbons or a nitrogenous hydrocarbon mixture wherein said nitrogenous hydrocarbons, an oxygen-containing gas, with or without ammonia, with or without water, with or without a gas comprising nitrogen oxides and with or without other essentially inert feed gas constituents are introduced into a flame reaction zone, react in the flame reaction zone and a post-reaction zone at a temperature of from 1000 to 1800° C. for a reaction time of 0.03 to 0.3 s to form a cleavage gas which comprises hydrogen cyanide, carbon oxides, hydrogen, water, ammonia, nitrogen, light hydrocarbons with or without other cleavage gas constituents, the atomic C/N ratio in the reaction zones being from 1 to 7 and the atomic air ratio λato being <0.6, said cleavage gas being cooled and separated.
Dependencies are inferred from the claim text.