Substituted cycloalkanes, and use thereof as cationic polymerization initiators
AssigneesBASF SE, Ludwig-Maximilians-Universitaet
InventorsDarijo Mijolovic, Mirjam Herrlich-Loos, Gabriele Lang, Herbert Mayr
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Abstract
Substituted 7- to 12-membered cycloalkanes which have leaving groups, in particular chlorine atoms, on tertiary ring carbons, a process for preparing them and their use as initiators for cationic polymerization, in particular the cationic polymerization of isobutene are described. Preferred compounds are 1,4-dichloro-1,4-dimethylcyclooctane, 1,5-dichloro-1,5-dimethylcyclooctane and mixtures thereof. They are prepared by addition of hydrogen chloride onto appropriately substituted cycloalkapolyenes.
Claims11
A substituted cycloalkane of the formulae Ia, Ib, and Ic:
- wherein
- R is C1-C6-alkyl;
- X is halogen, OR1 or OCOR1, wherein R1 is C1-C6-alkyl;
- and
- o=1 and p=2, or
- o=1 or 2, p=2 or 3 and o+p=4, or
- o=1 or 2, p=3 or 4 and o+p=5.
Dependencies are inferred from the claim text.