# US 7,277,178 B2 · Coherent photothermal interferometric spectroscopy system and method for chemical sensing > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 7,277,178 B2 - Document ID: US7277178B2 - Status: Granted - Kind: B2 - Application number: 10/947,640 - Filed: 2005-01-13 - Published: 2005-05-19 - Granted: 2007-10-02 - Earliest claimed: 2003-09-22 - Assignees: CeLight, Inc. - Inventors: Isaac Shpantzer; Jacob B. Khurgin; Pak Shing Cho; Yaakov Achiam - Web page: https://patentgrep.com/patent/US7277178B2 ## CPC - G01N 21/171: {with calorimetric detection, e.g. with thermal lens detection} - G01N 21/39: using tunable lasers - G01N 21/65: Raman scattering - G01J 3/4338: {Frequency modulated spectrometry} - G01N 2021/655: {Stimulated Raman} - G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q) - G01J: MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY (light sources F21, H01J, H01K, H05B; investigating properties of materials by optical means G01N) ## Abstract A photo-thermal, interferometric spectroscopy system is disclosed that provides information about a chemical at a remote location. A first light source assembly is included that emits a first beam. The first beam has one or more wavelengths that interact with the chemical and change a refractive index of the chemical. A second light source produces a second beam. The second beam interacts with the chemical resulting in a third beam with a phase change that corresponds with the change of the refractive index of the chemical. A detector system is positioned remote from the chemical to receive at least a portion of the third beam. The detector system provides information on a phase change in the third beam relative to the second beam that is indicative of at least one of, absorption spectrum and concentration of the chemical. ## Claims ### Claim 1 A photo-thermal, interferometric spectroscopy system that provides information about a chemical at a remote location, comprising: a first light source assembly that emits a first beam, the first beam having one or more wavelengths that interact with the chemical and change a refractive index of the chemical; a second light source that produces a second beam, the second beam interacting with the chemical resulting in a third beam with a phase change that corresponds with the change of the refractive index of the chemical; and a detector system positioned remote from the chemical to receive at least a portion of the third beam, the detector system providing information on a phase change in the third beam relative to the second beam that is indicative of at least one of, absorption spectrum and concentration of the chemical. ### Claim 2 (depends on 1) The system of claim 1, wherein the chemical is in the form of a gas, liquid or solid. ### Claim 3 (depends on 1) The system of claim 1, wherein the chemical is incorporated in a gas, liquid or solid medium. ### Claim 4 (depends on 1) The system of claim 1, wherein the chemical is selected from, an explosive device, a fuzing and one or mere fuzing components. ### Claim 5 (depends on 1) The system of claim 1, wherein the chemical is at least one species in an explosive. ### Claim 6 (depends on 1) The system of claim 1, wherein the chemical is at an explosive site, a site of pollution and a site of a chemical weapon. ### Claim 7 (depends on 1) The system of claim 1, wherein the remote location is selected from, an explosive standoff location, outside of a blast range, inside a blast range, and at an entry point. ### Claim 8 (depends on 1) The system of claim 1, wherein the detector system is positioned from the remote location a distance that provides that the detector system does not physically touch the chemical. ### Claim 9 (depends on 1) The system of claim 1, wherein the detector system is positioned at least 1–1000 meters from the chemical. ### Claim 10 (depends on 1) The system of claim 1, wherein the detector system is configured to detect the chemical in an amount of 1 part per trillion or more. ### Claim 11 (depends on 1) The system of claim 1, wherein the first and second beams cross each other or propagating collinearly together. ### Claim 12 (depends on 1) The system of claim 1, wherein the first light source beam generates a spectrum of wavelengths in the near and far infrared ranges. ### Claim 13 (depends on 12) The system of claim 12, wherein the first light assembly, comprises: a light source that produces a light source beam; a comb generator positioned to receive the light source beam and produce a plurality of near IR wavelengths; and a non-linear mixer positioned to receive the plurality of near IR wavelengths and produce the first beam, the first beam having mid IR wavelengths that are directed to the chemical. ### Claim 14 (depends on 13) The system of claim 13, wherein the near IR wavelengths are 0.7 to 2.5 micrometer. ### Claim 15 (depends on 13) The system of claim 13, wherein the mid IR wavelengths are 2.5–20 micrometer. ### Claim 16 (depends on 1) The optical system of claim 1, wherein the first light source assembly is tuneable in a range 0.2–20 micrometer. ### Claim 17 (depends on 1) The system of claim 1, further comprising abeam directing device positioned to direct the first beam to the interrogated chemical. ### Claim 18 (depends on 17) The system of claim 17, wherein the beam directing device is selected from, a mechanical device, a minor on gimbals and a MEMS device. ### Claim 19 (depends on 1) The optical system of claim 1, wherein the second light source is a pulsed light source and the second beam is pulsed with a series of pulses. ### Claim 20 (depends on 19) The optical system of claim 19, wherein the first light source is a pulsed light source. ### Claim 21 (depends on 20) The optical system of claim 20, wherein a time between pulses of the second beam is less than equal to a time between pulses of the first beam. ### Claim 22 (depends on 19) The system of claim 19, wherein the number of pulses in a series is from 2 to N, where N is an integer up to 105. ### Claim 23 (depends on 1) The system of claim 1, further comprising: a beam directing device positioned to direct the second beam to the chemical. ### Claim 24 (depends on 1) The system of claim 1 wherein the third beam is the second beam following its interaction with the chemical. ### Claim 25 (depends on 1) The system of claim 1 wherein at least one of the second and third beams pass through at least a portion of the chemical. ### Claim 26 (depends on 1) The optical system of claim 1, wherein the detector system is an interferometer. ### Claim 27 (depends on 1) The optical system of claim 1, wherein the detector system includes a coherent balanced receiver. ### Claim 28 (depends on 27) The optical system of claim 27, wherein the coherent receiver provides homodyne detection of the third beam. ### Claim 29 (depends on 27) The system of claim 27, wherein the detector system, comprises: a first coupler coupled to the first input and producing at least a first and second output; a second coupler coupled to the second input and producing at least a first and second output; a third coupler coupled to the first output of the first coupler and to the first output of the second coupler; a fourth coupler coupled to the second output of the first coupler and to the second output of the second coupler; first and second crossing waveguides with an angle selected to minimize crosstalk and losses between the first and second cross waveguides, the first crossing waveguide connecting one of the first or second outputs from the first coupler with an input of the fourth coupler, the second crossing waveguide connecting one of the first or second outputs from the second coupler with an input of the third coupler; a first phase shifter coupled to the first and second waveguides, the first and second waveguides connecting one of the outputs of the first or second coupler and one of the inputs of the third or fourth couplers, wherein the first, second, third and fourth couplers, the two crossing waveguides and the phase shifter are each formed as part of a single planar chip made of an electro-optical material. ### Claim 30 (depends on 27) The optical device of claim 27, wherein the optical device is selected from at least one of, an integrated device, a free-space optical link device, and a fiber optics device. ### Claim 31 (depends on 29) The optical device of claim 29, wherein the integrated device is a chip on one or more pieces of optical crystal. ### Claim 32 (depends on 27) The optical device of claim 27, wherein the electro-optical material is selected from at least one of, a semiconductor and a ferroelectric material. ### Claim 33 (depends on 32) The optical device of claim 32, wherein the ferroelectric material is selected from LiNbO3 and LiTaO3. ### Claim 34 (depends on 27) The optical system of claim 27, wherein the detector system includes a digital processor configured to measure a phase shift of the third beam that is induced by the first beam. ### Claim 35 (depends on 27) The detection system of claim 27, wherein a phase noise induced by fluctuations of a refractive index of an air path between the chemical and the detector system and vibration of a back-scattered surface is adaptively compensated using a DSP engine. ### Claim 36 (depends on 1) The system of claim 1, further comprising: a wavelengths data base that links a chemical constituent to one or more selective photo-thermal processes. ### Claim 37 (depends on 1) The system of claim 1, wherein a photo-thermal process of at least a portion of the chemical is initiated by absorption of at least a first photon from the first beam. ### Claim 38 (depends on 37) The system of claim 37, wherein a photo-thermal process of at least a portion of the chemical is initiated by populating an energy level of the chemical by a multi-photon absorption. ### Claim 39 (depends on 37) The system of claim 37, wherein a photo-thermal process of at least a portion of the chemical is initiated by populating molecular energy levels of the chemical through stimulated Raman excitation using two or more laser beams with different wavelengths. ### Claim 40 (depends on 37) The system of claim 37, wherein a photo-thermal process of at least a portion of the chemical is initiated by or more photo-thermal absorption/excitation lines of the chemical. ### Claim 41 (depends on 1) The system of claim 1, wherein detection at different wavelengths is done consequentially in time. ### Claim 42 (depends on 1) The system of claim 1, wherein the detector detects one chemical at a time. ### Claim 43 (depends on 1) The system of claim 1, wherein the detector detects a plurality of chemicals at one time. ### Claim 44 (depends on 1) The optical system of claim 1, wherein the system is configured to provide an identify of the chemical as well as isotopes of the chemical. ### Claim 45 (depends on 1) The system of claim 1, wherein the first and second beams share one or more light-sources. ### Claim 46 (depends on 1) Another embodiment includes the optical system of claim 1, wherein the second beam includes of least a first branch and a second branch, the first branch being directed into a volume that contains chemical and the second beam is directed to a position external to the chemical. ### Claim 47 A method for determining information about a chemical at a remote location, comprising: directing a first beam to a remote locution where a chemical is present, the first beam having one or more wavelengths that interact with the chemical and changing a refractive index of the chemical; directing a second beam that interacts with the chemical, forming a third beam having a phase change relative to the second beam that corresponds with a change of a refractive index of the chemical; receiving at least a portion of the third beam at a detection system positioned remote from the chemical; and measuring a phase shift of the third beam that is induced by the first beam and is indicative of at least one of, absorption spectrum and concentration of the chemical. ### Claim 48 (depends on 47) The method of claim 47, wherein the chemical is in the form of a gas, liquid or solid. ### Claim 49 (depends on 47) The method of claim 47, wherein the chemical is incorporated in a gas, liquid or solid medium. ### Claim 50 (depends on 47) The method of claim 47, wherein the chemical is selected from, an explosive device, a fuzing and one or more fuzing components. ### Claim 51 (depends on 47) The method of claim 47, wherein the chemical is at least one species in an explosive. ### Claim 52 (depends on 47) The method of claim 47, wherein the chemical is at an explosive site, a site of pollution and a site of a chemical weapon. ### Claim 53 (depends on 47) The method of claim 47, wherein the remote location is selected from, an explosive standoff location, outside of a blast range, inside a blast range, and at an entry point. ### Claim 54 (depends on 47) The method of claim 47, wherein the detector system is positioned at least 1 meter from the chemical. ### Claim 55 (depends on 47) The method of claim 47, wherein the detector system is positioned at least 1–1000 meters from the chemical. ### Claim 56 (depends on 47) The method of claim 47, wherein the detector system is configured to detect the chemical in an amount of 1 part per trillion or more. ### Claim 57 (depends on 47) The method of claim 47, wherein the first and second beams cross each other or propagating collinearly together. ### Claim 58 (depends on 47) The method of claim 47, wherein the first light beam is produced from a first light source that generates a spectrum of wavelengths in near and far infrared range. ### Claim 59 (depends on 47) The method of claim 47, wherein the first light source comprises: a light source that produces a first beam; a comb generator positioned to receive the first beam to produce a beam with a plurality of near IR wavelengths; and a non-liner mixer positioned to receive the beam with the plurality of near IR wavelengths and produce the first light beam, the first beam having mid IR wavelengths that are directed to the chemical. ### Claim 60 (depends on 59) The method of claim 59, wherein the near IR wavelengths are 0.7 to 2.5 micrometer. ### Claim 61 (depends on 59) The method of claim 59, wherein the mid IR wavelengths are 2.5–20 micrometer. ### Claim 62 (depends on 59) The optical system of claim 59, wherein the first light source is tuneable in a range 0.3–20 micrometer. ### Claim 63 (depends on 47) The method of claim 47, further comprising directing the first beam with a beam directing device to the chemical. ### Claim 64 (depends on 47) The method of claim 47, wherein the second light beam is produced from a second light source, the second light source being a pulsed light source and the second beam being a pulsed beam with a series of pulses. ### Claim 65 (depends on 47) The method of claim 47, wherein the first light source is a pulsed light source. ### Claim 66 (depends on 47) The method of claim 47, wherein the second beam is a coherent pulsed beam. ### Claim 67 (depends on 66) The method of claim 66, wherein the coherent pulses beam includes a series of a plurality of a pulses in series with an interruption between each series of pulses. ### Claim 68 (depends on 67) The method of claim 67, wherein the number of pulses in a series is from 2 to N, where N is an integer up to 105. ### Claim 69 (depends on 47) The method of claim 47 wherein the third beam is the second beam following its interaction with the chemical, wherein the third beam propagates in essentially the same direction as the second beam. ### Claim 70 (depends on 69) The method of claim 69 wherein the second or third beam passes through at least a portion of the chemical. ### Claim 71 (depends on 47) The method of claim 47, wherein the detector system is an interferometer. ### Claim 72 (depends on 47) The method of claim 47, wherein the detector system includes a coherent balanced receiver. ### Claim 73 (depends on 47) The method of claim 47, wherein the coherent receiver provides homodyne detection of the third beam. ### Claim 74 Another embodiment of the method 47, wherein the second beam includes of least a first branch and a second branch, the first branch being directed into a volume that contains the chemical and the second beam is directed to a position external to the chemical.