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US 7,273,957 B2Granted
Process for the production of gasoline stocks
AssigneeCatalytic Distillation Technologies
InventorsAmarjit S. Bakshi, Mitchell E. Loescher, Nishit Sahay
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Abstract
A process for the production of gasoline stocks wherein lower molecular weight olefins are first oligomerized and the oligomers then hydrogenated. In the first instance the oligomerization is carried out in a single pass fixed bed boiling point reactor. The oligomers are then hydrogenated in a distillation column reactor.
Claims2
A process for the production of gasoline components comprising the steps of:
- (a) feeding a hydrocarbon stream containing C3-C5 olefins to a single pass downflow fixed bed reactor containing a cationic acidic resin catalyst under oligomerization conditions within the range of 120° F. to 300° F. wherein the temperature in said reactor maintains a boiling mixture in said reactor thereby reacting at least a portion of said C3-C5 olefins with each other or themselves to form oligomers;
- (b) feeding the effluent from said single pass downflow fixed bed reactor and hydrogen to a distillation column reactor containing hydrogenation catalyst consisting essentially of Pd on an alumina support in a distillation reaction zone;
- (c) concurrently in said distillation reaction zone under conditions of concurrent hydrogenation and distillation:
- (i) contacting said oligomers with said hydrogen in the presence of said hydrogenation catalyst at a temperature of 150° F.-350° F., at 10 to 150 psig to hydrogenate a portion of said oligomers to the corresponding alkanes;
- and
- (ii) separating the corresponding alkanes from other hydrocarbons and hydrogen by fractional distillation;
- (d) removing said corresponding alkanes from said distillation column reactor at a point below said distillation zone;
- (e) removing said other hydrocarbons and hydrogen from said distillation column as overheads;
- (f) cooling said overheads to separate said other hydrocarbons from said hydrogen;
- and
- (g) recycling a portion of said other hydrocarbons to said distillation column reactor as reflux.
8 more elements
Dependencies are inferred from the claim text.