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US 7,255,808 B2Granted
Functional fluid compositions containing erosion inhibitors
AssigneeSolutia Inc.
InventorsDavid C. Silverman, Timothy K. Hirzel
Life of this patent
Estimating the term…
Abstract
A phosphate ester-based functional fluid composition incorporating at least one erosion inhibitor selected from the erosion inhibitors of the invention. The phosphate ester-based functional fluids are particularly useful as aviation hydraulic fluids.
Claims96
A functional fluid composition comprising:
- (a) a base stock comprising a phosphate ester, and
- (b) an effective erosion inhibiting amount of at least one erosion inhibitor selected from compounds represented by the formulas
- or mixtures thereof;
- wherein said erosion inhibitor(s) used in said functional fluid composition at least partially ionize, and the effective amount of said erosion inhibitor(s) used in said functional fluid composition is essentially soluble in said functional fluid compositions;
- wherein Rf is selected from fluoroalkyl, fluoroaryl, fluoroaralkyl, fluoroalkaryl, fluorocycloalkyl, fluoroallcoxyalkyl, or fluoropolyalicoxyalkyl groups;
- Y and Y′ are independently selected from C, S, S(═A), P—Rf, P—OR, or P—NRR′;
- A and A′ are independently selected from O or NR;
- X is selected from N, or C—R″;
- Z is selected from Y′(═A′)—Rf, H, OC(═O)—Rf, or R1—NH—(SO2—Rf);
- R and R′ are independently selected from H, alkyl, fluoroalkyl, aryl, fluoroaryl, alkaryl, aralkyl, fluoroalkaryl, or fluoroaralkyl;
- R″ is selected from H, alkyl, fluoroalkyl, aryl, fluoroaryl, alkaryl, aralkyl, fluoroalkaryl, fluoroaralkyl, or —Y(═A)—R2;
- R2 is selected from alkyl, fluoroalkyl, aryl, fluoroaryl, alkaryl, aralkyl, fluoroalkaryl, or fluoroaralkyl;
- R1 is selected from unsubstituted or fluoro-substituted alkylene, cycloalkylene, alkarylene, aralkylene, or arylene groups;
- Rf3 is selected from fluoroalkylene, fluoroarylene, fluoroaralkylene, fluoroalkarylene, fluoroalkoxyalkylene, or fluoropolyalkoxyalkylene moieties;
- M is a cation of valence n;
- and n is 1, 2, 3 or 4;
- with the proviso that when both of Y and Y′ are S(═A), X is N, A is O and n is less than 2 then only one Rf is fluoroalkyl, fluoroalkaryl, fluorocycloalkyl, fluoroalicoxyalkyl, or fluoropolyalicoxyalkyl in Formula I.
14 more elements
A functional fluid composition comprising:
- (a) a basestock comprising a phosphate ester, and
- (b) an effective erosion inhibiting amount of at least one erosion inhibitor selected from compounds represented by the formulas
- or mixtures thereof;
- wherein Rf1 and Rf2 are independently selected from fluoroalkyl, fluoroaralkyl, fluoroalkaryl, fluorocycloalkyl, fluoroaryl, fluoroalkoxyalkyl, or fluoropolyalkoxyalkyl groups;
- M is a cation of valence n;
- n is 1, 2, 3 or 4;
- R is selected from H, alkyl, fluoroalkyl, aryl, fluoroaryl, alkaryl, fluoroalkaryl, aralkyl, or fluoroaralkyl;
- R1 is selected from unsubstituted or fluoro-substituted alkylene, cycloalkylene, alkarylene, aralkylene, or arylene groups;
- and Rf3 is selected from fluoroalkylene, fluoroarylene, fluoroaralkylene, fluoroalkarylene, fluoroalkoxyalkylene, or fluoropolyalkoxyalkylene moieties;
- and
- wherein said erosion inhibitor at least partially ionizes in said functional fluid, and said effective amount of said erosion inhibitor is essentially soluble in said functional fluid;
- with the proviso that in Formula (i), when n is 2, only one of Rf1 and Rf2 is selected from the group consisting of fluoroalkyl, fluoroalkaryl, fluorocycloalkyl, fluoroallcoxyalkyl, or fluoropolyallcoxyalkyl and
- with the further proviso that in Formula (iv), when n is 2 then Rf1 is not selected from the group consisting of fluoroalkyl, fluoroalkaryl, fluorocycloalkyl, fluoroalkoxyalkyl, or fluoropolyalkoxyalky.
10 more elements
Dependencies are inferred from the claim text.