Water-soluble aspartate
AssigneeBayer MaterialScience AG
InventorsBurkhard Köhler, Meike Niesten, Joachim Simon, Christian Wamprecht
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Abstract
The present invention relates to new water-soluble polyaspartic esters and also to their use in aqueous coating compositions.
Drawings
Claims11
Hydrophilic polyaspartic esters of the general formula (I)
- where
- R is C1-C4 alkyl radical,
- A and A′ independently of one another are hydrogen or methyl,
- X is an n-valent aliphatic, araliphatic or cycloaliphatic radical having 1 to 20 carbon atoms and optionally containing ether bridges,
- l and m are natural numbers from 0 to 10 whose sum l+m=1 to 20, and
- n is a natural number from 1 to 3.
Process for preparing hydrophilic polyaspartic esters comprising reacting maleic esters of the general formula (II)
- where
- R is a C1-C4 alkyl radical,
- A and A′ independently of one another are hydrogen or methyl, and
- l and m independently of one another are natural numbers from 0 to 10 and their sum l+m=1 to 20
- with an n-valent amine of the formula (III)
- where
- X is an n-valent aliphatic, araliphatic or cycloaliphatic radical having 1 to 20 carbon atoms and optionally containing ether bridges and
- n is a natural number from 1 to 3
- at temperatures of 0 to 100° C., preferably of 15 to 50° C.
Dependencies are inferred from the claim text.