Magnesium-containing carrier components and application thereof to olefin polymerization
AssigneeMitsui Chemicals, Inc.
InventorsYasushi Nakayama, Hideki Bando, Yoshiho Sonobe, Makoto Mitani, Terunori Fujita
Life of this patent
Estimating the term…
Loading patent…
AssigneeMitsui Chemicals, Inc.
InventorsYasushi Nakayama, Hideki Bando, Yoshiho Sonobe, Makoto Mitani, Terunori Fujita
Estimating the term…
Solid fine particles which contain a magnesium atom, an aluminum atom and a C1-20 alkoxy group simultaneously, are insoluble in a hydrocarbon solvent, and have an average particle diameter of 3 to 80 μm, and an olefin polymerization catalyst containing the solid fine particles and a transition metal compound in the groups 3 to 11 in the periodic table, exhibit a very high olefin polymerization activity without combination with an expensive organoaluminum oxy compound or organoboron compound and maintains a high activity in polymerization for a long time, and an olefin polymer excellent in powdery properties can be produced by using the olefin polymerization catalyst. The transition metal compound in the groups 3 to 11 in the periodic table includes a transition metal compound having a ligand containing two or more atoms selected from a boron atom, a nitrogen atom, an oxygen atom, a phosphorus atom and a sulfur atom.
A carrier component suitable as an olefin polymerization catalyst, which is insoluble in a hydrocarbon solvent, is in the form of solid fine particles having an average particle diameter of 3 to 80 μm, and contains a magnesium atom, an aluminum atom and a C1-20 alkoxy group simultaneously, wherein the molar ratio of magnesium atom to aluminum atom (Mg/Al) is in the range of 40 to 150, and the molar ratio of alkoxy group to aluminum atom (alkoxy group/Al) is in the range of 0.2 to 2.0.
Dependencies are inferred from the claim text.