Glass ceramic having a low thermal expansion
AssigneeSchott AG
InventorsIna Mitra, Jochen Alkemper
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Abstract
The present invention relates to a novel glass ceramic having a low or small average thermal expansion together with good polishability and processability, to the use of the glass ceramic according to the invention, and to optical components made of the glass ceramic. In particular, a glass ceramic is provided which comprises the following composition (in % by weight based on oxide): SiO2 50–70 Al2O3 17–32 P2O5 3–12 Li2O 2.5–5 Na2O 0–2 K2O 0–2 MgO 0–2 CaO 0.1–4 BaO 0–<1 SrO 0–2 ZnO 0–4 TiO2 1.5–5 ZrO2 0–2.5.
Claims14
An optical component comprising a substrate, said substrate comprising a glass ceramics which has a coefficient of thermal expansion CTE of from −0.5×10−6/K to +0.5×10−6/K in a temperature range of from 0 to 50° C., which is free of BaO, which is free of arsenic, and which has a composition, in % by weight based on oxide content, comprising:
- SiO2
- 50–70
- Al2O3
- 17–32
- P2O5
- 3–12
- Li2O
- 2.5–5
- Na2O
- 0–2
- K2O
- 0–2
- MgO
- 0–2
- CaO
- 0.1–4
- SrO
- 0–2
- ZnO
- 0–4
- TiO2
- 1.5–5
- ZrO2
- 0–2.5.
A method for producing an optical component comprising the steps of:
- providing a substrate for an optical element which comprises a glass ceramic which has a coefficient of thermal expansion CTE of from −0.5×10−6/K to +0.5×10−6/K in a temperature range of from 0 to 50° C.,
- superpolishing the surface of the substrate to a surface roughness HSFR of at most 0.5 nm rms, and
- processing the superpolished surface by a beam processing method to a fine surface figure error of at most 0.5 nm rms and a surface roughness MSFR of at most 0.5 nm rms, the surface roughness HSFR being substantially undeteriorated even after said processing has ended so as to still be at most 0.5 nm rms;
- wherein said glass ceramic is free of BaO, free of arsenic, and has a composition, in percent by weight based on oxide content, comprising:
- SiO2
- 50–70
- Al2O3
- 17–32
- P2O5
- 3–12
- Li2O
- 2.5–5
- Na2O
- 0–2
- K2O
- 0–2
- MgO
- 0–2
- CaO
- 0.1–4
- SrO
- 0–2
- ZnO
- 0–4
- TiO2
- 1.5–5
- ZrO2
- 0–2.5.
A glass ceramic having a coefficient of thermal expansion CTE of from −0.5×10−6/K to +0.5×10−6/K in a temperature range of from 0 to 50° C., and which is free of BaO, free of arsenic and which has a composition, in % by weight based on oxide content, comprising:
- SiO2
- 50–70
- Al2O3
- 17–32
- P2O5
- 3–12
- Li2O
- 2.5–5
- Na2O
- 0–2
- K2O
- 0–2
- MgO
- 0–2
- CaO
- 0.1–4
- SrO
- 0–2
- ZnO
- 0–4
- TiO2
- 1.5–5
- ZrO2
- 0–2.5.
Dependencies are inferred from the claim text.