Silver halide color photographic photosensitive material

A silver halide color photographic photosensitive material comprising, on a support, at least one yellow color-forming photosensitive silver halide emulsion layer, at least one magenta color-forming photosensitive silver halide emulsion layer, and at least one cyan color-forming photosensitive silver halide emulsion layer,

• wherein at least one dye-forming coupler is contained in the same layer as at least one compound represented by formula (Ph), and
• wherein the at least one dye-forming coupler is a yellow dye-forming coupler represented by formula (Ia) set forth below or a magenta dye-forming coupler, represented by any one of formulae (M-I) to (M-X) set forth below:
• wherein, in formula (Ia), Qa represents a group of non-metal atoms that forms a 5- to 7-membered ring in combination with the —N═C—N((CH2)3O—R11a)—;
• R11a represents an alkyl group having carbon atoms of 4 or more and 8 or less;
• R2a represents a substituent:
• R14a represents a primary alkyl group;
• ma represents an integer of 0 or more and 4 or less;
• when ma is 2 or more, R2as may be the same or different, and they may combine together to form a ring;
• and X1 represents a hydrogen atom, or a group capable of being spilt-off upon a coupling reaction with an oxidized product of a developing agent;
• wherein, in formula (M-I), Y1 and Y2 each independently represent a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group, a heterocyclic group, an alkoxy group, a cycloalkoxy group, or a heterocyclic oxy group;
• R1 represents an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, an amido group, a carbamoyl group, a sulfinyl group, a sulfonyl group, an amino group, a cyano group, a nitro group, or a hydroxyl group;
• R2 represents a substituted or unsubstituted, alkyl group, alkenyl group, cycloalkyl group, aryl group, or heterocyclic group;
• when R2 has a substituent, the substituent is selected from an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, an amido group, a sulfinyl group, a sulfonyl group, an amino group and a hydroxyl group, each of which may be further substituted;
• X represents a halogen atom;
• p represents 0, 1, or 2;
• and when p is 2, a plurality of R1s may be the same or different;
• wherein, in formula (M-II), Y3 and Y4 each independently represent a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group, a heterocyclic group, an alkoxy group, a cycloalkoxy group, an aryloxy group, or a heterocyclic oxy group;
• R3 represents an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, a carbamoyl group, an amido group, a sulfinyl group, a sulfonyl group, an amino group, a cyano group, a nitro group, or a hydroxyl group;
• R4 represents a substituted or unsubstituted, alkyl group, alkenyl group, cycloalkyl group, aryl group, or heterocyclic group;
• when R4 has a substituent, the substituent is selected from an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, a carbamoyl group, an amido group, a sulfinyl group, a sulfonyl group, an amino group and a hydroxyl group, each of which may be further substituted;
• X represents a halogen atom;
• q represents 0, 1, or 2;
• and when q is 2, a plurality of R3s may be the same or different;
• wherein, in formula (M-III), L1 represents —NR7— or —O—;
• R5 represents an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, a carbamoyl group, an amido group, a sulfinyl group, a sulfonyl group, an amino group, a cyano group, a nitro group, or a hydroxyl group;
• R6 represents a substituted or unsubstituted, alkyl group, alkenyl group, cycloalkyl group, aryl group, or heterocyclic group;
• R7 represents a hydrogen atom, or a substituted or unsubstituted, alkyl group, alkenyl group, cycloalkyl group, aryl group, or heterocyclic group;
• when R6 and R7 have a substituent, the substituent is selected from an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, a carbamoyl group, an amido group, a sulfinyl group, a sulfonyl group, an amino group and a hydroxyl group, each of which may be further substituted;
• X represents a halogen atom;
• r represents 0, 1, or 2;
• and when r is 2, a plurality of R5s may be the same or different;
• wherein, in formula (M-IV), L2 represents —NR10- or —O—;
• R8 represents an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, a carbamoyl group, an amido group, a sulfinyl group, a sulfonyl group, an amino group, a cyano group, a nitro group, or a hydroxyl group;
• R9 represents a substituted or unsubstituted, alkyl group, alkenyl group, cycloalkyl group, aryl group, or heterocyclic group;
• R10 represents a hydrogen atom, or a substituted or unsubstituted, alkyl group, alkenyl group, cycloalkyl group, aryl group, or heterocyclic group;
• when R9 and R10 have a substituent, the substituent is selected from an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, a carbamoyl group, an amido group, a sulfinyl group, a sulfonyl group, an amino group and a hydroxyl group, each of which may be further substituted;
• X represents a halogen atom;
• s represents 0, 1, or 2;
• and when s is 2, a plurality of R8s may be the same or different;
• wherein, in formula (M-V), R11 represents an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, a carbamoyl group, an amido group, a sulfinyl group, a sulfonyl group, an amino group, a cyano group, a nitro group, or a hydroxyl group;
• R12 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, a heterocyclic oxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, a cycloalkoxycarbonyl group, an aryloxycarbonyl group, a heterocyclic oxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, a carbamoyl group, an amido group, a sulfinyl group, a sulfonyl group, an amino group, or a hydroxyl group;
• R13 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, a heterocyclic oxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, a cycloalkoxycarbonyl group, an aryloxycarbonyl group, a heterocyclic oxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, a carbamoyl group, an amido group, a sulfonyl group, an amino group, a sulfinyl group, or a hydroxyl group;
• R14 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, a heterocyclic oxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, a cycloalkoxycarbonyl group, an aryloxycarbonyl group, a heterocyclic oxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, a carbamoyl group, an amido group, a sulfinyl group, a sulfonyl group, an amino group, or a hydroxyl group;
• X represents a halogen atom;
• t represents 0, 1, or 2;
• and when t is 2, a plurality of R11s may be the same or different;
• wherein, in formula (M-VI), R15 represents an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, a carbamoyl group, an amido group, a sulfinyl group, a sulfonyl group, an amino group, a cyano group, a nitro group, or a hydroxyl group;
• R16, R17, and R18 each independently represent a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, a heterocyclic oxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, a cycloalkoxycarbonyl group, an aryloxycarbonyl group, a heterocyclic oxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, a carbamoyl group, an amido group, a sulfinyl group, a sulfonyl group, an amino group, or a hydroxyl group;
• X represents a halogen atom;
• u represents 0, 1, or 2;
• and when u is 2, a plurality of R15s may be the same or different;
• wherein, in formula (M-VII), R19 and R20 each independently represent an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, a carbamoyl group, an amido group, a sulfinyl group, a sulfonyl group, an amino group, a cyano group, a nitro group, or a hydroxyl group;
• v and w each independently represent 0 or 1, but both v and w are not 0s at the same time;
• L3 represents —NR22— or —O—;
• x represents 0 or 1;
• R21 represents a substituted or unsubstituted, alkyl group, alkenyl group, cycloalkyl group, aryl group, or heterocyclic group;
• R22 represents a hydrogen atom, or a substituted or unsubstituted, alkyl group, alkenyl group, cycloalkyl group, aryl group, or heterocyclic group;
• when R21 and R22 have a substituent, the substituent is selected from an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, a carbamoyl group, an amido group, a sulfinyl group, a sulfonyl group, an amino group and a hydroxyl group, each of which may be further substituted;
• and X represents a halogen atom;
• wherein, in formula (M-VIII), R23 and R24 each independently represent a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group, or a heterocyclic group;
• R25 represents a substituted or unsubstituted, alkyl group, alkenyl group, cycloalkyl group, aryl group, or heterocyclic group;
• R26 represents an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, a carbamoyl group, an amido group, a sulfinyl group a sulfonyl group, an amino group, a cyano group, a nitro group, or a hydroxyl group;
• y represents 0, 1, or 2;
• when y is 2, a plurality of R26s may be the same or different;
• L4 represents a divalent linking group selected from —(C═O)—, —(C═O)—O—, —O—(C═O)—, —(C═O)—NR27—, —NR27—(C═O)—, —NR27—(C═O)—NR27—, —O—(C═O)—NR27—, —NR27—(C═O)—O—, —O—, —S—, —SO—, —SO2—, and —NR27—;
• R27 represents a hydrogen atom, or a substituted or unsubstituted, alkyl group, alkenyl group, cycloalkyl group, aryl group, or heterocyclic group;
• when R25 and R27 have a substituent, the substituent is selected from an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, a carbamoyl group, an amido group, a sulfinyl group, a sulfonyl group, an amino group and a hydroxyl group, each of which may be further substituted;
• and X represents a halogen atom;
• wherein, in formula (M-IX), R28 represents a substituted or unsubstituted, alkyl group, alkenyl group, cycloalkyl group, aryl group, or heterocyclic group;
• when R28 has a substituent, the substituent is selected from an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, an alkoxy group, a cycloalkoxy group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, a carbamoyl group, an amido group, a sulfinyl group, a sulfonyl group, an amino group and a hydroxyl group, each of which may be further substituted;
• R29 represents an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, a halogen atom, a cycloalkoxy group, an aryloxy group, an alkylthio group, a cycloalkylthio group, an arylthio group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonamido group, a sulfamoyl group, a ureido group, an acyl group, an acyloxy group, a carbamoyl group, an amido group, a sulfinyl group, a sulfonyl group, an amino group, a cyano group, a nitro group, or a hydroxyl group;
• X represents a halogen atom;
• z represents 0, 1, or 2;
• and when z is 2, a plurality of R29s may be the same or different;
• wherein, in formula (M-X), R31 represents a tertiary alkyl group;
• R32 and R33 each independently represent a hydrogen atom or a substituent;
• X represents a hydrogen atom, a halogen atom, or an aryloxy group;
• A and B each independently represent —CO— or —SO2—;
• α represents 0 or 1;
• R34 represents a hydrogen atom, an alkyl group or an aryl group;
• R35 represents an alkyl group, an aryl group, an alkoxy group, an alkylamino group or an arylamino group;
• and R34 and R35 may bond with each other to form a 5- to 7-membered ring;
• wherein, in formula (Ph), Rb1 represents an aliphatic group, an aryl group, a carbamoyl group, an acylamino group, a carbonyl group, or a sulfonyl group;
• and Rb2 to Rb5 each independently represent a hydrogen atom, a halogen atom, a hydroxyl group, an aliphatic group, an aryl group, a heterocyclic group, an alkyloxy group, an aryloxy group, a heterocyclic oxy group, an oxycarbonyl group, an acyl group, an acyloxy group, an oxycarbonyloxy group, a carbamoyl group, an acylamino group, a sulfonyl group, a sulfinyl group, a sulfamoyl group, an alkylthio group, or an arylthio group.