High-speed positive-working photothermographic system
AssigneeEastman Kodak Company
InventorsMichael R. Roberts, Paul B. Gilman, Donald L. Black, Kurt M. Schroeder
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AssigneeEastman Kodak Company
InventorsMichael R. Roberts, Paul B. Gilman, Donald L. Black, Kurt M. Schroeder
Estimating the term…
The present invention is directed to a method of forming a positive image in a photothermographic element comprising a potentially negative-working emulsion wherein fog density development is imagewise inhibited in exposed areas of the image upon thermal development. In one embodiment of the invention, a density-inhibiting agent is released during thermal development which agent inhibits the thermal development of unexposed silver salts in the exposed areas relative to the unexposed areas. The method preferably comprises imagewise exposing the film with a non-solarizing amount of radiation/energy to form a latent image and thermally developing the latent image in a single development step to produce a positive image in the element. The present invention is also directed to a photothermographic element that can be used in the present process in which a positive image characterized by high speed and discrimination is formed when exposed and thermally heated above 150° C.
A method of forming a positive image in a photothermographic element that has been imagewise exposed to form a latent image, which element has at least one imaging layer comprising a potentially negative-working emulsion, said method comprising imagewise exposing said element and thermally developing the imagewise exposed element to produce a positive image in said imaging layer, wherein at the temperature of thermal development substantial imagewise inhibition occurs with respect to the exposed areas of the positive image relative to the unexposed areas of the positive image, wherein thermal development of unexposed silver grains in the exposed areas is inhibited relative to the unexposed areas and wherein negative image development is inhibited, wherein the imaging layer comprises at least two organic non-halide silver compounds, a first and a second organic non-halide silver compound, wherein a density-inhibiting agent is released by at least one of the organic non-halide silver compounds, and wherein the second organic non-halide silver compound that releases a density-inhibiting agent has a pKsp that is at least 0.5 greater than the pKsp of said first organic non-halide silver compound.
A method of processing a photothermographic element tat has been imagewise exposed, said element having at least one light-sensitive imaging layer comprising a potentially negative-working emulsion comprising light-sensitive silver halide, at least two organic non-halide silver compounds, a first and a second organic non-halide silver compound, wherein a density-inhibiting agent is released by at least one of the organic non-halide silver compounds, and wherein the second organic non-halide silver compound that releases a density-inhibiting agent has a pKsp that is at least 0.5 greater than the pKsp of said first organic non-halide silver compound, and an effective amount of a density inhibitor, which method in order comprises:
A method of forming a positive image in a photothermographic element that has been imagewise exposed to form a latent image, which element has at least one imaging layer comprising a potentially negative-working emulsion, said method comprising imagewise exposing said element and thermally developing the imagewise exposed element to produce a positive image in said imaging layer, wherein at the temperature of thermal development substantial imagewise inhibition occurs with respect to the exposed areas of the positive image relative to the unexposed areas of the positive image, wherein thermal development of unexposed silver grains in the exposed areas is inhibited relative to the unexposed areas and wherein negative image development is inhibited, and wherein the method further comprises the presence in the element of a developer or precursor thereof, an oxidized developer scavenging agent to remove oxidized developer as it is formed during the thermal development, light-sensitive silver halide, and wherein the imaging layer comprises at least two organic non-halide silver salts, a first and a second organic silver compound, wherein a density-inhibiting agent is released by at least one of the organic silver salts, wherein the second organic silver salt that releases a density-inhibiting agent has a pKsp that is at least 0.5 greater than the pKsp of said first organic silver salt, and wherein the second organic silver salt that releases a density-inhibiting agent comprises a mercapto-functional compound and the first organic silver salt comprises a salt of a benzotriazole-functional compound.
Dependencies are inferred from the claim text.