A method of writing data, using photoelectrons, on a data storage medium comprising a lower electrode, an insulation layer deposited on the lower electrode, a photoelectron emission layer deposited on the insulation layer and having a plurality of protrusions from which photoelectrons are emitted due to collision between the protrusions and photons, and a dielectric layer deposited on the photoelectron emission layer and storing the photoelectrons emitted from the photoelectron emission layer by using a data storage apparatus comprising a stage supporting the data storage medium, a scanner driving the stage, a probe placed over the data storage medium and including a tip forming an electric field with the data storage medium and a cantilever supporting the tip placed at its one end so as to maintain a predetermined distance between the data storage medium and the tip, a circuit unit applying a driving signal, a data write signal, and a data erase signal to the scanner and the probe and detecting a data read signal, and a light source irradiating light on the data storage medium, the method comprising:
- placing the probe over the data storage medium and forming an electric field by applying voltage to the lower electrode of the data storage medium and the tip;
- and
- writing data on the data storage medium by irradiating light on the surface of the data storage medium where the electric field is formed so as to make photons collide with the photoelectron emission layer and storing photoelectrons emitted from the protrusions due to the collision between the protrusions and the photons in the dielectric layer.