Method of removing entrained sulfuric acid from alkylate
AssigneeCatalytic Distillation Technologies
InventorLawrence A. Smith, Jr.
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Abstract
An improvement in the alkylation of olefins with isoalkanes in the presence of sulfuric acid wherein the sulfuric acid is removed from the product by a mechanical coalescer means prior to fractionation. No water wash or caustic treatment is required. Any sulfonates or sulfonic esters are removed by hydrodesulfurization or decomposition catalyst in a separate reactor or in either the deisobutanizer (DIB) or debutanizer (DB) column.
Claims2
A process for the removal of entrained sulfuric acid and water from the alkylation of olefins with isoalkanes in the presence of sulfuric acid comprising passing the alkylation product through a deentrainment device containing coalescer material to remove the sulfuric acid therefrom and recovering an effluent comprising alkylation product wherein the effluent from the deentrainment device is contacted with a decomposition catalyst prepared in the form of a catalytic distillation structure said decomposition catalyst being contained within the stripping section of a deisobutanizer (DIB) column which separates isobutane from the alkylation product to convert any sulfonates and sulfonic esters contained therein to their constituent components.
A process for the removal of entrained sulfuric acid and water from the alkylation of olefins with isoalkanes in the presence of sulfuric acid comprising passing the alkylation product through a deentrainment device containing coalescer material to remove the sulfuric acid therefrom and recovering an effluent comprising alkylation product wherein the effluent from the deentrainment device is contacted with a decomposition catalyst prepared in the form of a catalytic distillation structure said decomposition catalyst being contained within the stripping section of a debutanizer (DB) column which separates normal butane from the alkylation product to convert any sulfonates and sulfonic esters contained therein to their constituent components.
Dependencies are inferred from the claim text.