Process for the conversion of methane
AssigneeThe Penn State Research Foundation
InventorsAyusman Sen, Minren Lin
Life of this patent
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Abstract
A process for the facile two-step synthesis of methanol from methane is disclosed. In accordance with the invention, an appropriate combination of initiator and reaction medium is employed to achieve methane conversion in very high selectivity and yield under near-ambient temperature.
Claims4
A process for converting methane to methanesulfonic acid, whereby methane conversion exceeds 35% of total methane, comprising:
- a) dissolving H2S2O8 in a mixture of methanesulfonic acid and sulfur trioxide;
- and
- b) contacting methane at 300 to 1400 psi with a solution resulting from said mixture at about 40–60° C.
A process for converting methane to methanesulfonic acid, whereby sulfur trioxide conversion exceeds 90% of total sulfur trioxide when used as the limiting reagent, comprising:
- a) dissolving H2S2O8 in a mixture of methanesulfonic acid and sulfur trioxide;
- and
- b) contacting methane at 300 to 1400 psi with a solution resulting from said mixture at about 40–60° C.
A process for converting methane to methanesulfonic acid, whereby selectivity to methanesulfonic acid exceeds 90% of total product, comprising:
- a) dissolving H2S2O8 in a mixture of methanesulfonic acid and sulfur trioxide;
- and
- b) contacting methane at 300 to 1400 psi with a solution resulting from said mixture at about 40–60° C.
A process for converting methane to methanesulfonic acid, whereby the one-pass yield of methanesulfonic acid exceeds 35% of total methane, comprising:
- a) dissolving H2S2O8 in a mixture of methanesulfonic acid and sulfur trioxide;
- and
- b) contacting methane at 300 to 1400 psi with a solution resulting from said mixture at about 40–60° C.
Dependencies are inferred from the claim text.