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US 7,115,549 B2Granted
Composition comprising macrocyclic tetra-amido metal complex as bleaching catalyst
AssigneeCarnegie Mellon University
InventorsSarah Dixon, Peter Leslie Gratton, John Oakes
Life of this patent
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Abstract
The present invention provides a laundry bleaching composition comprising: a) a macrocycilc tetra amido N-donor metal-ligand complex (preferably, 5,6-benzo-3,8,11,13-tetraoxo-2,2,9,9,12,12-hexamethyl-1,4,7,10-tetraaza-cyclo-tridecane), and b) an alkyl benzene sulphonate surfactant, said composition being substantially devoid of any added peroxygen bleach or a peroxy-based or peroxy-generating bleach system.
Claims12
A bleaching composition comprising:
- a) an alkyl benzene sulphonate surfactant, and
- b) a macrocyclic tetra amido N-donor metal ligand complex, having the structure as shown below:
- wherein:
- B1, B3 and B4 each represent a bridging group having zero, one two or three carbon containing nodes for substitution, and B2 represents a bridging group having at least one carbon containing node for substitution, each said node containing a C(R), C(R1)(R2) or C(R)2,
- each R substituent is the same or different from the remaining R substituents, and
- (1) is selected from the group consisting of alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl, alkynyl, alkylaryl, halogen, alkoxy, phenoxy and combinations thereof, or
- (2) form a substituted or unsubstituted benzene ring of which two carbons on the ring form nodes in the B-unit;
- M is a transition metal ion;
- L is an axial ligand;
- and,
- Q is an alkali metal or tetra-alkyl ammonium or tetra-phenyl phosphonium counter-ion and,
- said composition being devoid of any added peroxygen bleach or a peroxy based or peroxyl-generating bleach system.
9 more elements
Dependencies are inferred from the claim text.