Gel electrolyte and fuel cell employing the same
AssigneeSamsung SDI Co., Ltd.
InventorYuichi Aihara
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Abstract
The present invention is related to a gel electrolyte composed of a mixture comprising an acid and a high molecular compound. The acid is capable of causing the polymer compound to swell. The polymer compound may comprise a high molecular compound, such as, a partially methylated polybenzimidazole where at least one substituent R group of the polybenzimidazole structure is a methyl group. Additionally, the present invention is related to a fuel cell employing gel electrolyte of the present invention. The gel electrolyte of the present invention has good proton conductivity for a long period of time under conditions having a relative humidity in the range of about 0% to about 50% at an operating temperature in the range of about 100° C. to about 300° C.
Claims6
A gel electrolyte comprising:
- an acid;
- and
- a polymer compound, wherein the polymer compound is a partially methylated polybenzimidazole represented by Formula (1) where at least one substituent R group of the polybenzimidazole structure is a methyl group:
- where R is CH3 or H and n is a number in the range of about 10 to about 100,000
- wherein the partially methylated polybenzimidazole is a polymethylated benzimidazole with a degree of methylation less than about 80 mol %, and
- wherein the partially methylated polybenzimidazole comprises a mixture of poly(N-methylbenzimidazole) with a degree of methylation of about 100 mol % and polybenzimidazole with a degree of methylation of about 0 mol % and a poly(N-methylbenzimidazole) content of less than about 80 mol %.
A fuel cell, comprising:
- a pair of electrodes;
- and
- an electrolyte membrane interposed between the electrodes, wherein a part or the whole of the electrolyte membrane is a gel electrolyte comprising:
- an acid;
- and
- a polymer compound, wherein the polymer compound is a partially methylated polybenzimidazole represented by Formula (1) where at least one substituent R group of the polybenzimidazole structure is a methyl group:
- where R is CH3 or H and n is a number in the range of about 10 to about 100,000
- wherein the partially methylated polybenzimidazole is a polymethylated benzimidazole with a degree of methylation less than about 80 mol %, and
- wherein the partially methylated polybenzimidazole comprises a mixture of poly(N-methylbenzimidazole) with a degree of methylation of about 100 mol % and polybenzimidazole with a degree of methylation of about 0 mol % and a poly(N-methylbenzimidazole) content of less than about 80 mol %.
A gel electrolyte comprising:
- an acid;
- and
- a polymer compound, wherein the polymer compound is a partially methylated polybenzimidazole represented by Formula (1) where at least one substituent R group of the polybenzimidazole structure is a methyl group:
- where R is CH3 or H and n is a number in the range of about 10 to about 100,000
- wherein the partially methylated polybenzimidazole is a polymethylated benzimidazole with a degree of methylation less than about 80 mol %, and
- wherein the partially methylated polybenzimidazole comprises a mixture of polymethylated benzimidazole with a degree of methylation of X mol % and polybenzimidazole with a degree of methylation of about 0 mol % and when the weight of the polymethylated benzimidazole is A and the weight of the polybenzimidazole is B, f obtained by an equation of f(mol %)=AX/(A+B) (where X is in the range of about 80 mol % to about 100 mol %) is less than about 80 mol %.
A fuel cell, comprising:
- a pair of electrodes;
- and
- an electrolyte membrane interposed between the electrodes, wherein a part or the whole of the electrolyte membrane is a gel electrolyte comprising:
- an acid;
- and
- a polymer compound, wherein the polymer compound is a partially methylated polybenzimidazole represented by Formula (1) where at least one substituent R group of the polybenzimidazole structure is a methyl group:
- where R is CH3 or H and n is a number in the range of about 10 to about 100,000
- wherein the partially methylated polybenzimidazole is a polymethylated benzimidazole with a degree of methylation less than about 80 mol %, and
- wherein the partially methylated polybenzimidazole comprises a mixture of polymethylated benzimidazole with a degree of methylation of X mol % and polybenzimidazole with a degree of methylation of about 0 mol % and when the weight of the polymethylated benzimidazole is A and the weight of the polybenzimidazole is B, f obtained by an equation of f(mol %)=AX/(A+B) (where X is in the range of about 80 mol % to about 100 mol %) is less than about 80 mol %.
Dependencies are inferred from the claim text.