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US 7,094,859 B2Granted
Cross-linkable polymer blends containing alkoxysilane-terminated polymers
AssigneeConsortium Fuer Elektrochemische Industrie GmbH
InventorsWolfram Schindler, Uwe Scheim, Bernd Pachaly
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Abstract
Alkoxysilane-terminated polymers prepared by reacting an isocyanatoalkoxysilane, preferably an isocyanatodialkyalkoxysilane, with an isocyanate-reactive prepolymer, can provide chain extension even when a monoalkoxy-functional silane, while retaining suitable reactivity profiles. The products are useful in sealants, caulks, coatings, and moldings.
Claims19
A crosslinkable polymer blend, comprising at least one polymer A having endgroups of the formula (1)
- -L-CH2—SiR1a(OR2)3-a (1)
- wherein
- L is a divalent linking group selected from —O—CO—NH—, —N(R3)—CO—NH—, —S—CO—NH—,
- R1 is an optionally halogen-substituted alkyl, cycloalkyl, alkenyl or aryl radical having 1–10 carbon atoms,
- R2 is an alkyl radical having 1–6 carbon atoms or an ω-oxyalkylalkyl radical having a total of 2–10 carbon atoms,
- R3 is hydrogen, an optionally halogen-substituted cyclic, linear or branched C1 to C18 alkyl or alkenyl radical or a C6 to C18 aryl radical, and
- a is an integer from 0 to 2,
- with the proviso that the fraction of the endgroups of the general formula (1) where a=2, relative to all the endgroups of the polymers present in the mixture which have alkoxysilane endgroups, is from 5% to 100%.
5 more elements
Dependencies are inferred from the claim text.