Conjugated diene rubber gel, rubber compositions containing the same and process for production of conjugated diene rubber
AssigneeZeon Corporation
InventorsMasao Nakamura, Koichi Endo
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AssigneeZeon Corporation
InventorsMasao Nakamura, Koichi Endo
Estimating the term…
A conjugated diene rubber gel comprising 80–99 weight % of conjugated diene monomer units and 20–1 weight % of aromatic vinyl monomer units and having a swelling index of 16 to 70 as measured in toluene. A rubber vulcanizate made from a rubber composition comprising this conjugated diene rubber gel and a rubber capable of being crosslinked with sulfur exhibits good abrasion resistance and low heat-build up without deterioration of mechanical properties, and thus, is suitable for tire materials. This conjugated diene rubber gel can be produced with high efficiency by emulsion-polymerization of a monomer mixture comprising 50–99.9 weight % of a conjugated diene monomer, 0–30 weight % of an aromatic vinyl monomer, 0–20 weight % of a crosslinking monomer.
A process for producing a conjugated diene-aromatic vinyl copolymer rubber, characterized in that a monomer mixture comprising 15% to 69.8% by weight of a conjugated diene monomer, 30.1% to 65% by weight of an aromatic vinyl monomer, 0% to 20% by weight of other ethylenically unsaturated monomer and 0.1% to 5% by weight of a crosslinking monomer is copolymerized by an emulsion polymerization procedure,
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