Thermally development imaging materials having backside stabilizers
AssigneeEastman Kodak Company
InventorsSteven H. Kong, Kumars Sakizadeh, William D. Ramsden
Life of this patent
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Abstract
Thermally developable photothermographic materials comprise a backside layer that includes a backside stabilizer to reduce fog formation in high humidity conditions, thereby providing improved shelf stability. Useful backside stabilizers include an amine organic base whose conjugate acid has a pKa greater than 5. These backside stabilizers can be provided particularly in non-photosensitive compositions that include an antihalation composition.
Claims21
A photothermographic film pack or stack comprising a plurality of photothermographic materials,
- each photothermographic material comprising a support having on a frontside thereof, one or more thermally-developable imaging layers comprising a binder and in reactive association, a photosensitive silver halide, a non-photosensitive source of reducible silver ions, and a reducing composition for said non-photosensitive source reducible silver ions,
- and on a non-photosensitive backside of said support, a backside layer comprising a binder and an amine organic base as a backside stabilizer, the conjugate acid of said organic base having a pKa greater than 5 and being present in an amount of at least 0.01 mmol/m2,
- wherein said backside stabilizer is represented by the following Structure I:
- wherein R1, R2, and R3 are independently chosen from hydrogen, —C(R4)═NR5, —C(NR6R7)═NR5, substituted or unsubstituted alkyl groups having 1 to 18 carbon atoms, substituted or unsubstituted cycloalkyl groups, substituted or unsubstituted alkenyl groups having 2 to 18 carbon atoms, substituted or unsubstituted carbocyclic aryl groups having 6 or 10 carbon atoms in the aromatic rings, substituted or unsubstituted heterocyclic groups having 5 to 10 carbon, nitrogen, sulfur, and oxygen atoms, and R4, R5, R6, and R7 are independently chosen from the same groups as R1, R2, and R3, or any one or more of R1, R2, R3, R4, R5, R6, and R7 as defined above may be joined with each other and/or the central nitrogen atom to complete one or more substituted or unsubstituted heterocyclic ring(s).
A photographic film pack or stack comprising a plurality of photothermographic materials,
- each photothermographic material comprising transparent polymer support having on a frontside thereof:
- a) one or more thermally-developable imaging layers comprising a hydrophobic binder and in reactive association:
- a photosensitive silver bromide, silver iodobromide, or a mixture thereof,
- a non-photosensitive source of reducible silver ions that comprises one or more silver carboxylates at least one of which is silver behenate, and
- a reducing composition for said non-photosensitive source reducible silver ions, and
- b) on a non-photosensitive backside of said support, an antihalation layer comprising an antihalation composition, an antistatic material, and a backside stabilizer that is one or more of the following Compounds (AB-1) through (AB-24), said backside stabilizer being present in an amount of from about 0.05 to about 2 mmol/m2,
Dependencies are inferred from the claim text.