Organophotoreceptor with a charge transport material having two (9-fluorenylidene)malononitrile groups
AssigneeSamsung Electric Co., Ltd.
InventorsNusrallah Jubran, Zbigniew Tokarski, Kam W. Law, Eric Morrison, Vytautas Getautis, Vygintas Jankauskas
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Abstract
Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula X-Z-X′ where X and X′ are, each independently, a (9-fluorenylidene)malononitrile group, and Z is a linking group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.
Claims22
An organophotoreceptor comprising an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising:
- (a) a charge transport material having the formula
- X-Z-X′
- where X and X′, each independently, have the formula
- where Y is O—CH2—CH2—O, S, or NR8 and R8 is H, an alkyl group, an alkenyl group, an aromatic group, or a heterocyclic group, and Z is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 1 and 30, inclusive, and one or more of the methylene groups may be replaced by O, S, C═O, Si═O, S(═O)2, P(═O)2, an aromatic group, a heterocyclic group, an aliphatic cyclic group, a Si(R1)(R2) group, a BR3 group, a NR4 group, a CHR5 group, or a CR6R7 group where R1, R2, R3, R4, R5, R6, and R7 are, each independently, H, halogen, hydroxyl, thiol, an alkoxy group, an alkyl group, an alkenyl group, an aromatic group, a heterocyclic group, or a part of a cyclic ring;
- and
- (b) a charge generating compound.
An electrophotographic imaging apparatus comprising:
- (a) a light imaging component;
- and
- (b) an organophotoreceptor oriented to receive light from the light imaging component, the organophotoreceptor comprising an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising:
- (i) a charge transport material having the formula
- X-Z-X′
- where X and X′, each independently, have the formula
- where Y is O—CH2—CH2—O, S, or NR8 and R8 is H, an alkyl group, an alkenyl group, an aromatic group, or a heterocyclic group, and Z is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 1 and 30, inclusive, and one or more of the methylene groups may be replaced by O, S, C═O, Si═O, S(═O)2, P(═O)2, an aromatic group, a heterocyclic group, an aliphatic cyclic group, a Si(R1)(R2) group, a BR3 group, a NR4 group, a CHR5 group, or a CR6R7 group where R1, R2, R3, R4, R5, R6, and R7 are, each independently, H, halogen, hydroxyl, thiol, an alkoxy group, an alkyl group, an alkenyl group, an aromatic group, a heterocyclic group, or a part of a cyclic ring;
- and
- (ii) a charge generating compound.
An electrophotographic imaging process comprising;
- (a) applying an electrical charge to a surface of an organophotoreceptor comprising an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising
- (i) a charge transport material having the formula
- X-Z-X′
- where X and X′, each independently, have the formula
- where Y is O—CH2—CH2—O, S, or NR8 and R8 is H, an alkyl group, an alkenyl group, an aromatic group, or a heterocyclic group, and Z is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 1 and 30, inclusive, and one or more of the methylene groups may be replaced by O, S, C═O, Si═O, S(═O)2, P(═O)2, an aromatic group, a heterocyclic group, an aliphatic cyclic group, a Si(R1)(R2) group, a BR3 group, a NR4 group, a CHR5 group, or a CR6R7 group where R1, R2, R3, R4, R5, R6, and R7 are, each independently, H, halogen, hydroxyl, thiol, an alkoxy group, an alkyl group, an alkenyl group, an aromatic group, a heterocyclic group, or a part of a cyclic ring;
- and
- (ii) a charge generating compound.
- (b) imagewise exposing the surface of the organophotoreceptor to radiation to dissipate charge in selected areas and thereby form a pattern of charged and uncharged areas on the surface;
- (c) contacting the surface with a toner to create a toned image;
- and
- (d) transferring the toned image to substrate.
A charge transport material having the formula
- X-Z-X′
- where X and X′, each independently, have the formula
- where Y is O—CH2—CH2—O, S, or NR8 and R8 is H, an alkyl group, an alkenyl group, an aromatic group, or a heterocyclic group, and Z is a linking group having the formula —(CH2)m—, branched or linear, where m is an integer between 1 and 30, inclusive, and one or more of the methylene groups may be replaced by O, S, C═O, Si═O, S(═O)2, P(═O)2, an aromatic group, a heterocyclic group, an aliphatic cyclic group, a Si(R1)(R2) group, a BR3 group, a NR4 group, a CHR5 group, or a CR6R7 group where R1, R2, R3, R4, R5, R6, and R7 are, each independently, H, halogen, hydroxyl, thiol, an alkoxy group, an alkyl group, an alkenyl group, an aromatic group, a heterocyclic group, or a part of a cyclic ring.
Dependencies are inferred from the claim text.