An electrolytic cell for producing charged anode water suitable for surface cleaning or treatment, comprising cathode, middle and anode chambers, a fluorinated cation-exchange membrane provided to separate cathode and middle chambers from each other, a cathode closely attached to the cation-exchange membrane on the side facing the cathode chamber, and a middle chamber filled with fluorinated cation-exchange resins, provided on the other side of the cation-exchange membrane, the cation-exchange resins being arranged in such a way to come into contact with the fluorinated cation-exchange membrane in the cathode chamber side and with the anode in the anode chamber side, wherein the feed water is fed into the middle chamber and passed through the fluorinated cation-exchange resins to be recovered as the charged anode water.