Diazaphosphacycles
AssigneeWisconsin Alumni Research Foundation
InventorsClark R. Landis, Wiechang Jin, Jonathan S. Owen, Thomas P. Clark
Life of this patent
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Abstract
A diazaphosphacycle may be synthesized by reacting a phosphine with a diimine and optionally one or more equivalents of an acid halide, a sulfonyl halide, a phosphoryl halide, or an acid anhydride in the substantial absence of O2 to form the diazaphosphacycle. The phosphine has the formula R1—PH2 where R1 is a substituted or unsubstituted aryl group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted cycloalkyl group, or a substituted or unsubstituted ferrocenyl group.
Claims12
A diazaphosphacycle, comprising a compound having the formula III and salts of the compound
- wherein
- R1 is selected from the group consisting of substituted and unsubstituted aryl groups, substituted and unsubstituted alkyl groups, substituted and unsubstituted alkenyl groups, substituted and unsubstituted cycloalkyl groups, and substituted and unsubstituted ferrocenyl groups;
- R2 and R3 are independently selected from the group consisting of substituted and unsubstituted aryl groups, substituted and unsubstituted alkyl groups, substituted and unsubstituted cycloalkyl groups, substituted and unsubstituted heterocyclyl groups, and substituted and unsubstituted ferrocenyl groups;
- R4 is selected from the group consisting of —H, substituted and unsubstituted alkyl groups, substituted and unsubstituted cycloalkyl groups, substituted and unsubstituted aryl groups, trialkylsilyl groups, triarylsilyl groups, alkyldiarylsilyl groups, dialkylarylsilyl groups, —C(═O)—R6 groups, —S(═O)2—R6 groups, —P(═O)R6R7 groups, and —C(═NR6)—R7 groups;
- R5 is selected from the group consisting of —H, substituted and unsubstituted alkyl groups, substituted and unsubstituted cycloalkyl groups, substituted and unsubstituted aryl groups, trialkylsilyl groups, triarylsilyl groups, alkyldiarylsilyl groups, dialkylarylsilyl groups, —C(═O)—R7 groups, —S(═O)2—R6 groups, —P(═O)R6R7 groups, and —C(═NR6)—R7 groups;
- R6 is selected from the group consisting of substituted and unsubstituted alkyl groups, substituted and unsubstituted alkenyl groups, substituted and unsubstituted cycloalkyl groups, substituted and unsubstituted aryl groups, —OH groups, substituted and unsubstituted alkoxy groups, substituted and unsubstituted aryloxy groups, —NH(alkyl) groups, —NH(aryl) groups, —N(aryl)2 groups, —N(alkyl)2 groups, —N(alkyl)(aryl) groups, —S-alkyl groups, and S-aryl groups;
- R7 is selected from the group consisting of substituted and unsubstituted alkyl groups, substituted and unsubstituted alkenyl groups, substituted and unsubstituted cycloalkyl groups, substituted and unsubstituted aryl groups, —OH groups, substituted and unsubstituted alkoxy groups, substituted and unsubstituted aryloxy groups, —NH(alkyl) groups, —NH(aryl) groups, —N(aryl)2 groups, —N(alkyl)2 groups, —N(alkyl)(aryl) groups, —S-alkyl groups, and S-aryl groups;
- R6 and R7 may be part of the same alkyl group, alkenyl group, or aryl group such that R4 and R5 together with the two nitrogen atoms of the diazaphosphacycle form a ring;
- and
- Y is a linking group selected from the group consisting of substituted and unsubstituted cycloalkyl groups, substituted and unsubstituted aryl groups, substituted and unsubstituted alkenyl groups, silyl groups, substituted alkyl groups, and groups having the formula —(CH2)n— wherein n is selected from the group consisting of 0, 1, 2, and 3.
Dependencies are inferred from the claim text.