Electro-optic polymers with tunable refractive index for optical waveguides
AssigneeThe United States of America as represented by the Secretary of the Navy
InventorsGeoffrey Andrew Lindsay, Peter Zarras, John D. Stenger-Smith
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Abstract
An electro-optic (EO) polymer that has a tunable index of refraction and are synthesized by the copolymerization a bisphenol monomer including a chromophoric structure and two diepoxy monomers. One diepoxy monomer includes at least one fluorine atom, and the second diepoxy monomer includes no fluorine atoms. The EO films are prepared by applying an electric field across the film as the film is heated to its glass transition temperature. The electric field is removed after cooling the film. The index of refraction of these nonlinear optical polymer materials is tuned between about 1.58 to about 1.66 (measured with light having a wavelength of about 1.3 microns).
Claims7
A linear polymer comprising:
- at least one bisphenol monomer attached to at least one chromophore, and at least one first diepoxy monomer including at least one fluorine atom, and at least one second diepoxy monomer including no fluorine atoms;
- and
- wherein said linear polymer includes an index of refraction between the range of about 1.58 to about 1.66 measured at a wavelength of about 1300 nm.
Dependencies are inferred from the claim text.