Hydrotreating polyester precursors
AssigneeEastman Chemical Company
InventorsZhufang Liu, Jeff Scott Howell, Charles Edwan Sumner, Jr.
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AssigneeEastman Chemical Company
InventorsZhufang Liu, Jeff Scott Howell, Charles Edwan Sumner, Jr.
Estimating the term…
A process comprising contacting a liquid polyester stream with hydrogen in the presence of a hydrogenation catalyst comprising a metal supported on the surface of silicon carbide at a metal dispersion of at least 0.5% or graphite at a metal dispersion of at least 10% to produce a treated liquid polyester stream. The treated stream may be polycondensed in the presence of a polycondensation catalyst to produce a polyester polymer having an It.V. of at least 0.55 dL/g. The liquid polyester stream desirably has a composition comprising: a) terephthalic acid residues, isophthalic acid residues, and/or naphthalenedicarboxylic acid residues and b) an average degree of polymerization of 0.5 to 20 and c) an acid number ranging from 5 to 600.
A melt phase process for the manufacture of a polyester polymer comprising:
Dependencies are inferred from the claim text.