Binding agents and binding agent compositions containing alkoxy silyl groups, methods of production and use
AssigneeHenkel Kommanditgesellschaft auf Aktien
InventorsJohann Klein, Wilfried Huebner, Gaby Schilling, Felicitas Kolenda, Wolfgang Klauck
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Abstract
A binder which is a graft polymer bearing at least two alkoxysilyl groups of the formula —Si(R1)m(OR2)3-m in which R1 and R2 are independently linear or branched alkyl groups containing 1 to 6 carbon atoms and m is an integer of 0 to 2. The graft polymer has graft branches on a graft base. The graft polymer contains at least 0.5% by weight, based on the graft base, of graft branches.
Claims15
A foam-generating composition comprising a propellant and a binder that comprises:
- a graft polymer bearing at least two alkoxysilyl groups of the formula:
- —Si(R1)m(OR2)3-m (I)
- in which R1 is a linear or branched alkyl group containing 1 to 6 carbon atoms, R2 is a linear or branched alkyl group containing 1 to 6 carbon atoms and m is an integer of 0 to 2, having graft branches on a graft base, the graft polymer containing at least 0.5% by weight, based on the graft base, of graft branches, wherein the graft polymer is obtained by reaction of a graft base or graft polymer bearing at least two reactive functional groups X with an alkoxysilane compound of the formula:
- Y—R3Si(R1)m(OR2)3-m (II)
- in which R1, R2, and m are as defined in the formula (I), R3 is a linear or branched alkyl group containing 2 to 24 carbon atoms, an optionally alkyl-substituted cycloalkyl group containing 4 to 24 carbon atoms, an optionally substituted aralkyl group containing 6 to 24 carbon atoms, an alkoxy group containing 2 to 10 carbon atoms, a polyoxyalkylene group containing 4 to 44 carbon atoms or an optionally alkyl-substituted aryl group containing 6 to 24 carbon atoms, and Y is at least one functional group which can react with the functional group X to form a covalent bond or Y and R3 together represent hydrogen, and wherein the graft polymer comprises at least one polymer selected from the group consisting of polyesters, polyethers, polyether esters, polyamides, polyurethanes, polycarbonates, polyacrylates, polymethacrylates, and polyvinyl esters.
A foam-generating binder composition comprising a propellant and:
- a) a polymer bearing alkoxysilyl groups obtained by
- a1) reaction of a polymer containing at least two reactive functional groups X with an alkoxysilane compound of the formula:
- Y—R3—Si(R1)m(OR2)3-m (II)
- in which R1 is a linear or branched alkyl group containing 1 to 6 carbon atoms, R2 is a linear or branched alkyl group containing 1 to 6 carbon atoms, R3 is a linear or branched alkyl group containing 2 to 24 carbon atoms, an optionally alkyl-substituted cycloalkyl group containing 4 to 24 carbon atoms, an optionally substituted aralkyl group containing 6 to 24 carbon atoms, an alkoxy group containing 2 to 10 carbon atoms, a polyoxyalkylene group containing 4 to 44 carbon atoms or an optionally alkyl-substituted aryl group containing 6 to 24 carbon atoms, m is an integer of 0 to 2 and Y is at least one functional group which can react with the functional group X to form a covalent bond or Y and R3 together represent hydrogen;
- or by
- a2) radical or ionic polymerization of a mixture of at least two monomers containing at least one olefinically unsaturated double bond, at least one olefinically unsaturated monomer containing at least one alkoxysilyl group of the formula:
- —Si(R1)m(OR2)3-m (I)
- in which R1 is a linear or branched alkyl group containing 1 to 6 carbon atoms, R2 is a linear or branched alkyl group containing 1 to 6 carbon atoms and m is an integer of 0 to 2,
- or a mixture of two or more such polymers, and
- b) at least one other polymer with or without an alkoxysilyl group which has a softening point of 30° C. to 250° C. (as measured by the ring and ball method),
- wherein the polymer bearing alkoxysilyl groups comprises at least one polymer selected from the group consisting of polyesters, polyethers, polyether esters, polyamides, polyurethanes, polycarbonates, polyacrylates, polymathacrylates, and polyvinyl esters.
A polymer foam obtained by foaming a binder that comprises:
- a graft polymer bearing at least two alkoxysilyl groups of the formula:
- —Si(R1)m(OR2)3-m (I)
- in which R1 is a linear or branched alkyl group containing 1 to 6 carbon atoms, R2 is a linear or branched alkyl group containing 1 to 6 carbon atoms and m is an integer of 0 to 2, having graft branches on a graft base, the graft polymer containing at least 0.5% by weight, based on the graft base, of graft branches, wherein the graft polymer comprises at least one polymer selected from the group consisting of polyesters, polyethers, polyether esters, polyamides, polyurethanes, polycarbonates, polyacrylates, polymethacrylates, and polyvinyl esters.
Dependencies are inferred from the claim text.