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US 7,064,231 B2Granted
Optically active diamines and their use in catalytic processes
AssigneeBayer Aktiengesellschaft
InventorJürgen Köcher
Life of this patent
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Abstract
The invention relates to stereoisomerically enriched diamines, to metal complexes comprising these diamines and also to their use in a process for asymmetrically reducing ketones using silanes, in particular polymethylhydrosiloxane, as reducing agents.
Claims16
Compounds of the formula (I)
- where
- * marks stereogenic carbon atoms which each independently have R- or S-configuration, excluding meso-forms and
- R1, R2, R3 and R4 are each independently hydrogen, C1–C12-alkyl, C4–C24-aryl or C5–C25-arylalkyl, or R1, R2, R3 and R4 together with ethylene bridge are 1,2-(C5–C8-cycloalkyl) and
- R5 and R6 are each independently radicals which are selected from the group of —COOR7, —CONR8R9, —CN or —PO(OR10)2 where R7, R8, R9 and R10 are each C1–C12-alkyl, C4–C24-aryl or C5–C25-arylalkyl, or NR8R9 as a whole is a cyclic amino radical having a total of 4 to 12 carbon atoms.
1 more element
Dependencies are inferred from the claim text.