Polytrimethylene terephthalate resins with improved properties
AssigneeZimmer, Inc.
InventorsEckhard Seidel, Bernd Gemmel, Karl-Heinz Heldmann
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Abstract
A composition comprising Polytrimethylene terephthalate (PTT) with a reduced emission of acrolein is obtained by contacting Polytrimethylene terephthalate (PTT) resin with an effective amount of a melt unstable, organic nitrogen-containing stabilizing compound. Such PTT resin has an acrolein formation rate at 280° C. of less than 15 ppm/minute. Preferably the residual acrolein content of the PTT resin is less than 5 ppm. Preferred additive compounds include amines, amino acids, amidines, urea and other N-compounds. The additive compounds are added to the polymer in molten state and/or to the resin, which is then processed to fibers, filaments, non-wovens, films and/or moldings.
Claims22
A method of reducing the emission of acrolein from a composition comprising polytrimethylene terephthalate (PTT), the method comprising contacting an effective amount of a melt unstable, organic nitrogen-containing stabilizing compound with the PTT composition.
Dependencies are inferred from the claim text.