Liquid-crystalline polyester solution composition
AssigneeSumitomo Chemical Company, Limited
InventorsSatoshi Okamoto, Shinji Ohtomo, Shiro Katagiri
Life of this patent
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Abstract
A liquid-crystalline polyester solution composition comprises an aprotic solvent and liquid-crystalline polyester. The liquid-crystalline polyester includes at least one of repeating unit selected from the group consisting of a repeating unit derived from aromatic diamine, a repeating unit derived from aromatic amine having a hydroxyl group and a repeating unit derived from aromatic amino acid, in from 10 to 35 mol % in the liquid-crystalline polyester.
Claims9
A method for producing a liquid-crystalline polyester solution composition comprising an aprotic solvent and a liquid-crystalline polyester comprising:
- at least one of the repeating units selected from the group consisting of a repeating unit derived from aromatic diamine, a repeating unit derived from aromatic amine having a hydroxyl group, and a repeating unit derived from aromatic amino acid, wherein the at least one of the repeating units is from 10 to 35 mol % in the liquid-crystalline polyester, and
- at least one of the repeating units represented by formulae (1), (2) and (3):
- —O—Ar1—CO— (1)
- —CO—Ar2—CO— (2)
- —X—Ar3—Y (3)
- wherein Ar1 represents 1,4-phenylene, 2,6-naphthalene or 4,4′-biphenylene, Ar2 represents 1,4-phenylene 1,3-phenylene or 2,6-naphthalene, Ar3 represents 1,4-phenylene of 1,3-phenylene, X represents —NH—, and Y represents —O— or —NH—,
- wherein the content of the repeating units represented by formulae (1), (2) and (3) is 30 to 80 mol %, 35 to 10 mol % and 35 to 10 mol %, respectively, in the liquid crystalline polyester
- and the method comprising the steps of:
- acylating at least one repeating unit selected from the group consisting of a hydroxycarboxylic acid providing the repeating unit represented by formula (1), an aromatic diamine, an aromatic amine having a hydroxyl group, an aromatic acid, and a repeating unit represented by formula (3) with an excess amount of a fatty acid anhydride to obtain an acylated compound,
- transesterification of the acylated compound and an aromatic dicarboxylic acid providing the repeating unit represented by formula (2) to obtain a liquid-crystalline polyester;
- dissolving the polyester in an aprotic solvent to obtain a liquid-crystalline polyester solution composition thereof.
A method for producing a liquid-crystalline polyester film comprising spreading a liquid-crystalline polyester solution composition over a support, and removing the solvent,
- wherein the liquid-crystalline polyester solution composition comprises an aprotic solvent and a liquid-crystalline polyester comprising:
- at least one of the repeating units selected from the group consisting of a repeating unit derived from aromatic diamine, a repeating unit derived from aromatic amine having a hydroxyl group, and a repeating unit derived from aromatic amino acid, wherein the at least one of the repeating units is from 10 to 35 mol % in the liquid-crystalline polyester, and
- at least one of the repeating units represented by formulae (1), (2) and (3):
- —O—Ar1—CO— (1)
- —CO—Ar2—CO— (2)
- —X—Ar3—Y (3)
- wherein Ar1 represents 1,4-phenylene, 2,6-naphthalene or 4,4′-biphenylene, Ar2 represents 1,4-phenylene, 1,3-phenylene or 2,6-naphthalene, Ar3 represents 1,4-phenylene or 1,3-phenylene, X represents —NH—, and Y represents —O— or —NH—,
- wherein the content of the repeating units represented by formulae (1), (2) and (3) is 30 to 80 mol %, 35 to 10 mol % and 35 to 10 mol %, respectively, in the liquid crystalline polyester.
Dependencies are inferred from the claim text.