Organosols comprising a chromophore, methods and uses
AssigneeSamsung Electronics Co., Ltd.
InventorsLeonard J. Stulc, Julie Y. Qian, James A. Baker
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Abstract
Amphipathic copolymers are provided comprising one or more S portions and one or more D portions. The copolymers have a chromophore covalently bonded thereto via a urethane, urea or amide linkage. These copolymers provide exceptionally useful components in toner compositions, because they provide easily prepared color-imparting particles that provide excellent color rendition.
Claims24
An electrophotographic toner composition comprising at least one amphipathic copolymer, the amphipathic copolymer comprising one or more S portions and one or more D portions wherein the S material portions and the D material portions have respective solubilities in a liquid carrier having a Kauri-butanol number less than 30 ml in which the amphipathic copolymer is prepared that are sufficiently different from each other such that the S material portions tend to be more solvated by the carrier while the D material portions tend to be more dispersed in the liquid carrier, the amphipathic copolymer having a chromophore covalently bonded thereto via a urethane, urea or amide linkage.
A method of making an electrophotographic toner composition comprising the steps of:
- A) preparing an amphipathic copolymer comprising at least one covalently bonded chromophore, comprising the steps of:
- a) providing a plurality of free radically polymerizable monomers, wherein at least one of the monomers comprises a first reactive functionality;
- b) free radically polymerizing the monomers in a solvent to form a first reactive functional polymer, wherein the monomers and the first reactive functional polymer are soluble in the solvent;
- c) reacting a compound having a second reactive functionality that is reactive with the first reactive functionality and also having free radically polymerizable functionality with the first reactive functional polymer under conditions such that at least a portion of the second reactive functionality of the compound reacts with at least a portion of the first reactive functionality of the polymer to form one or more linkages by which the compound is linked to the polymer, thereby providing an S material portion polymer with pendant free radically polymerizable functionality;
- d) copolymerizing ingredients comprising (i) the S material portion polymer with pendant free radically polymerizable functionality, (ii) one or more free radically polymerizable monomers, (iii) a chromophore comprising a third reactive functionality, and (iv) liquid carrier having a Kauri-butanol number less than 30 ml in which polymeric material derived from ingredients comprising the one or more additional monomers of ingredient (ii) is insoluble;
- wherein at least one of the ingredients (i) mid (ii) comprises available fourth reactive functionality;
- wherein one of the third and fourth reactive functionalities is an isocyanate functionality, and the other of the third and fourth reactive functionalities is selected from the group consisting of hydroxyl, amino, carboxyl or mixtures thereof;
- and wherein the copolymerizing occurs under conditions effective to form an amphipathic copolymer having S and D portions and a chromophore covalently bonded thereto via a urethane, urea or amide linkage;
- wherein the S material portions and the D material portions have respective solubilities in a liquid carrier having a Kauri-butanol number less than 30 ml in which the amphipathic copolymer is prepared that are sufficiently different from each other such that the S material portions tend to be more solvated by the carrier while the D material portions tend to be more dispersed in the liquid carrier;
- and
- B) formulating a toner composition comprising the amphipathic copolymer prepared in Step A) above.
Dependencies are inferred from the claim text.