Back to results
US 7,018,685 B2Granted
Fluorinated aromatic compounds and the use of the same in liquid crystal mixtures
AssigneeMerck Patent GmbH
InventorsWolfgang Schmidt, Rainer Wingen, Barbara Hornung
Life of this patent
Estimating the term…
Abstract
The invention relates to fluorinated aromatics of the formula (I) where X is CH2, C═O, CF2, O or S, Y is H or F, with the proviso that Y has to be F when X is CH2, and where the other parameters are as defined in claim 1, and also to their use in liquid-crystal mixtures, and also to liquid-crystal mixtures comprising these compounds and to liquid-crystal displays comprising these mixtures.
Claims10
A compound of the formula (I)
- where
- X is C═O,
- Y is H or F
- R1 and R2 are the same or different and are each hydrogen, or are a straight-chain or branched alkyl radical having from 1 to 16 carbon atoms or a straight-chain or branched alkenyl radical having from 2 to 16 carbon atoms where
- a) one or more nonadjacent and nonterminal CH2 groups may be replaced by —O—, —C(═O)O—, —O—C(═O)—, —O—C(═O)—O—, —C(═O)— or —Si(CH3)2—, and/or
- b) one CH2 group may be replaced by —C═C—, cyclopropane-1,2-diyl or cyclobutane-1,3-diyl, and/or
- c) one or more hydrogen atoms may be replaced by F or Cl, and/or
- d) the terminal CH3 group may be replaced by one of the following chiral groups (optically active or racemic):
- where R3 is a straight-chain or branched alkyl radical having from 1 to 12 carbon atoms or a straight-chain or branched alkenyl radical having from 2 to 12 carbon atoms, in each of which one or more nonadjacent and nonterminal CH2 groups may be replaced by —O— and/or one or more hydrogen atoms may be replaced by F or Cl,
- with the proviso where only one of R1 and R2 is a hydrogen,
- M1 and M2 are the same or different and are each —C(═O)—O—, —O—C(═O)—, —CH2—O—, —O—CH2—, —CF2—O—, —O—CF2—, —CH═CH—, —CF═CF—, —C≡C—, —CH2—CH2—C(═O)—O—, —O—C(═O)—CH2—CH2—, —CH2—CH2—, —CF2—CF2—, —(CH2)4— or a single bond,
- A1 and A2 are the same or different and are each 1,4-phenylene where one or two hydrogen atoms may be replaced by F, Cl or CN, pyridine-2,5-diyl where one hydrogen atom may be replaced by F, pyrimidine-2,5-diyl, 1,4-cyclohexylene where one or two hydrogen atoms may be replaced by CH3 or F, 1-cyclohexene-1,4-diyl where one hydrogen atom may be replaced by CH3 or F, or 1,3-dioxane-2,5-diyl,
- m and n are each independently 0 or 1, but in total not greater than 1.
10 more elements
A compound which is 2-butyloxy- 1,8-difluorofluorene.
Dependencies are inferred from the claim text.