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US 7,018,427 B2Granted
Dyeing composition containing a para-aminophenol or para-phenylenediamine compound substituted with a silane radical
AssigneeL'oreal
InventorHervé Richard
Life of this patent
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Abstract
A dyeing composition comprising at least one oxidation base chosen from para-aminophenol and para-phenylenediamine compounds substituted with a silane radical, and the dyeing method using this composition are disclosed. This composition is, for example, useful for dyeing keratinous fibers. The para-aminophenol and para-phenylenediamine compounds substituted with a silane radical are also disclosed.
Claims22
A dyeing composition, comprising:
- a medium appropriate for dyeing keratinous fibers and
- at least one oxidation base in said medium, wherein said at least one oxidation base is chosen from compounds corresponding to the following formula (I) and the corresponding cosmetically acceptable salts thereof:
- wherein:
- A is chosen from OH and NH2;
- R1 and R2, which may be identical or different, are chosen from hydrogen, linear and branched C1–C8 alkyl radicals, C1–C6 hydroxyalkyl radicals, and —Y—B radicals;
- R1 and R2 may form, together with the nitrogen atom to which they are attached, a 4- to 7-membered heterocycle, optionally substituted with at least one group chosen from C1–C3 alkyls, OH, NH2 and Z—B radicals;
- provided that when A is OH, then R1 and R2 are each hydrogen;
- R3 and R4, which may be identical or different, are chosen from hydrogen, C1–C4 alkyl radicals, C1–C4 alkoxy radicals, halogen atoms, and —Z—B radicals;
- Y is chosen from saturated and unsaturated, linear and branched C1–C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR, wherein R is chosen from hydrogen and C1–C4 alkyl radicals;
- Z is chosen from a covalent bond, and saturated and unsaturated, linear and branched C1–C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR′, wherein R′ is chosen from hydrogen, C1–C4 alkyl radicals, O—Y radicals, and NR″—Y radicals, wherein R″ is chosen from hydrogen and C1–C4 alkyl radicals;
- and
- B is chosen from —SiR5R6R7 groups, wherein R5, R6, and R7, which may be identical or different, are chosen from C1–C4 alkyl and phenyl radicals;
- provided that at least one of the groups R1, R2, R3, and R4 is chosen from —Y—B and Z—B.
10 more elements
A method for oxidation dyeing of keratinous fibers comprising applying to the keratinous fibers, in the presence of at least one oxidizing agent, a composition comprising at least one oxidation base chosen from compounds corresponding to the following formula (I) and the corresponding cosmetically acceptable salts thereof:
- wherein:
- A is chosen from OH and NH2;
- R1 and R2, which may be identical or different, are chosen from hydrogen, linear and branched C1–C8 alkyl radicals, C1–C6 hydroxyalkyl radicals, and —Y—B radicals;
- R1 and R2 may form, together with the nitrogen atom to which they are attached, a 4- to 7-membered heterocycle, optionally substituted with at least one group chosen from C1–C3 alkyls, OH, NH2 and Z—B radicals;
- provided that when A is OH, then R1 and R2 are each hydrogen;
- R3 and R4, which may be identical or different, are chosen from hydrogen, C1–C4 alkyl radicals, C1–C4 alkoxy radicals, halogen atoms, and Z—B radicals;
- Y is chosen from saturated and unsaturated, linear and branched C1–C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR, wherein R is chosen from hydrogen and C1–C4 alkyl radicals;
- Z is chosen from a covalent bond, and saturated and unsaturated, linear and branched C1–C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR′, wherein R′ is chosen from hydrogen, C1–C4 alkyl radicals, O—Y radicals, and NR″—Y radicals, wherein R″ is chosen from hydrogen and C1–C4 alkyl radicals;
- B is chosen from —SiR5R6R7 groups, wherein R5, R6, and R7, which may be identical or different, are chosen from C1–C4 alkyl and phenyl radicals;
- provided that at least one of the groups R1, R2, R3, and R4 is chosen from —Y—B and —Z—.
7 more elements
A multi-compartment device or multi-compartment dyeing kit comprising a first compartment comprising a composition comprising at least one oxidation base chosen from compounds corresponding to the following formula (I) and the corresponding cosmetically acceptable salts thereof:
- wherein:
- A is chosen from OH and NH2;
- R1 and R2, which may be identical or different, are chosen from hydrogen, linear and branched C1–C8 alkyl radicals, C1–C6 hydroxyalkyl radicals, and —Y—B radicals;
- R1 and R2 may form, together with the nitrogen atom to which they are attached, a 4- to 7-membered heterocycle, optionally substituted with at least one group chosen from C1–C3 alkyls, OH, NH2 and Z—B radicals;
- provided that when A is OH, then R1 and R2 are each hydrogen;
- R3 and R4, which may be identical or different, are chosen from hydrogen, C1–C4 alkyl radicals, C1–C4 alkoxy radicals, halogen atoms, and —Z—B radicals;
- Y is chosen from saturated and unsaturated, linear and branched C1–C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR, wherein R is chosen from hydrogen and C1–C4 alkyl radicals;
- Z is chosen from a covalent bond, and saturated and unsaturated, linear and branched C1–C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR′, wherein R′ is chosen from hydrogen, C1–C4 alkyl radicals, O—Y radicals, and NR″—Y radicals, wherein R″ is chosen from hydrogen and C1–C4 alkyl radicals;
- B is chosen from —SiR5R6R7 groups, wherein R5, R6, and R7, which may be identical or different, are chosen from C1–C4 alkyl and phenyl radicals;
- provided that at least one of the groups R1, R2, R3, and R4 is chosen from —Y—B and —Z—B, and
- a second compartment comprising an oxidizing composition.
8 more elements
A coloured product obtained by oxidation of a composition comprising:
- a medium appropriate for dyeing keratinous fibers and
- at least one oxidation base in said medium, wherein said at least one oxidation base is chosen from compounds corresponding to the following formula (I) and the corresponding cosmetically acceptable salts thereof:
- wherein:
- A is chosen from OH and NH2;
- R1 and R2, which may be identical or different, are chosen from hydrogen, linear and branched C1–C8 alkyl radicals, C1–C6 hydroxyalkyl radicals, and —Y—B radicals;
- R1 and R2 may form, together with the nitrogen atom to which they are attached, a 4- to 7-membered heterocycle, optionally substituted with at least one group chosen from C1–C3 alkyls, OH, NH2 and Z—B radicals;
- provided that when A is OH, then R1 and R2 are each hydrogen;
- R3 and R4, which may be identical or different, are chosen from hydrogen, C1–C4 alkyl radicals, C1–C4 alkoxy radicals, halogen atoms, and —Z—B radicals;
- Y is chosen from saturated and unsaturated, linear and branched C1–C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR, wherein R is chosen from hydrogen and C1–C4 alkyl radicals;
- Z is chosen from a covalent bond, and saturated and unsaturated, linear and branched C1–C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR′, wherein R′ is chosen from hydrogen, C1–C4 alkyl radicals, O—Y radicals, and NR″—Y radicals, wherein R″ is chosen from hydrogen and C1–C4 alkyl radicals;
- and
- B is chosen from —SiR5R6R7 groups, wherein R5, R6, and R7, which may be identical or different, are chosen from C1–C4 alkyl and phenyl radicals;
- provided that at least one of the groups R1, R2, R3, and R4 is chosen from —Y—B and —Z—B.
10 more elements
A method of manufacturing a coloured product comprising oxidizing a composition comprising at least one oxidation base chosen from compounds corresponding to the following formula (I) and the corresponding cosmetically acceptable salts thereof:
- wherein:
- A is chosen from OH and NH2;
- R1 and R2, which may be identical or different, are chosen from hydrogen, linear and branched C1–C8 alkyl radicals, C1–C6 hydroxyalkyl radicals, and —Y—B radicals;
- R1 and R2 may form, together with the nitrogen atom to which they are attached, a 4- to 7-membered heterocycle, optionally substituted with at least one group chosen from C1–C3 alkyls, OH, NH2 and Z—B radicals;
- provided that when A is OH, then R1 and R2 are each hydrogen;
- R3 and R4, which may be identical or different, are chosen from hydrogen, C1–C4 alkyl radicals, C1–C4 alkoxy radicals, halogen atoms, and —Z—B radicals;
- Y is chosen from saturated and unsaturated, linear and branched C1–C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR, wherein R is chosen from hydrogen and C1–C4 alkyl radicals;
- Z is chosen from a covalent bond, and saturated and unsaturated, linear and branched C1–C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR′, wherein R′ is chosen from hydrogen, C1–C4 alkyl radicals, O—Y radicals, and NR″—Y radicals, wherein R″ is chosen from hydrogen and C1–C4 alkyl radicals;
- B is chosen from —SiR5R6R7 groups, wherein R5, R6, and R7, which may be identical or different, are chosen from C1–C4 alkyl and phenyl radicals;
- provided that at least one of the groups R1, R2, R3, and R4 is chosen from —Y—B and —Z—B.
7 more elements
A composition for dyeing keratinous fibers comprising
- a medium appropriate for dyeing keratinous fibers and
- at least one oxidation base in said medium, wherein said at least one oxidation base is chosen from compounds corresponding to the following formula (I) and the corresponding cosmetically acceptable salts thereof:
- wherein:
- A is chosen from OH and NH2;
- R1 and R2, which may be identical or different, are chosen from hydrogen, linear and branched C1–C8 alkyl radicals, C1–C6 hydroxyalkyl radicals, and —Y—B radicals;
- R1 and R2 may form, together with the nitrogen atom to which they are attached, a 4- to 7-membered heterocycle, optionally substituted with at least one group chosen from C1–C3 alkyls, OH, NH2 and Z—B radicals;
- provided that when A is OH, then R1 and R2 are each hydrogen;
- R3 and R4, which may be identical or different, are chosen from hydrogen, C1–C4 alkyl radicals, C1–C4 alkoxy radicals, halogen atoms, and —Z—B radicals;
- Y is chosen from saturated and unsaturated, linear and branched C1–C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR, wherein R is chosen from hydrogen and C1–C4 alkyl radicals;
- Z is chosen from a covalent bond, and saturated and unsaturated, linear and branched C1–C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR′, wherein R′ is chosen from hydrogen, C1–C4 alkyl radicals, O—Y radicals, and NR″—Y radicals, wherein R″ is chosen from hydrogen and C1–C4 alkyl radicals;
- and
- B is chosen from —SiR5R6R7 groups, wherein R5, R6, and R7, which may be identical or different, are chosen from C1–C4 alkyl and phenyl radicals;
- provided that at least one of the groups R1, R2, R3, and R4 is chosen from —Y—B and —Z—B;
- and
- wherein the composition is effective in dyeing keratinous fibers.
12 more elements
A method for dyeing keratinous fibers comprising applying to the keratinous fibers a composition comprising
- a medium appropriate for dyeing keratinous fibers and
- at least one oxidation base in said medium, wherein said at least one oxidation base is chosen from compounds corresponding to the following formula (I) and the corresponding cosmetically acceptable salts thereof:
- wherein:
- A is chosen from OH and NH2;
- R1 and R2, which may be identical or different, are chosen from hydrogen, linear and branched C1–C8 alkyl radicals, C1–C6 hydroxyalkyl radicals, and —Y—B radicals;
- R1 and R2 may form, together with the nitrogen atom to which they are attached, a 4- to 7-membered heterocycle, optionally substituted with at least one group chosen from C1–C3 alkyls, OH, NH2 and Z—B radicals;
- provided that when A is OH, then R1 and R2 are each hydrogen;
- R3 and R4, which may be identical or different, are chosen from hydrogen, C1–C4 alkyl radicals, C1–C4 alkoxy radicals, halogen atoms, and —Z—B radicals;
- Y is chosen from saturated and unsaturated, linear and branched C1–C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR, wherein R is chosen from hydrogen and C1–C4 alkyl radicals;
- Z is chosen from a covalent bond, and saturated and unsaturated, linear and branched C1–C8 hydrocarbon chains that may include at least one hetero atom chosen from O, S, and NR′, wherein R′ is chosen from hydrogen, C1–C4 alkyl radicals, O—Y radicals, and NR″—Y radicals, wherein R″ is chosen from hydrogen and R1–C4 alkyl radicals;
- B is chosen from —SiR5R6R7 groups, wherein R5, R6, and R7, which may be identical or different, are chosen from C1–C4 alkyl and phenyl radicals;
- provided that at least one of the groups R1, R2, R3, and R4 is chosen from —Y—B and —Z—B.
9 more elements
Dependencies are inferred from the claim text.