US 7,008,970 B2 · Method for direct conversion of gaseous hydrocarbons to liquids

Abstract

A chemical reactor for direct conversion of hydrocarbons includes a dielectric barrier discharge plasma cell and a solid oxide electrochemical cell in fluid communication therewith. The discharge plasma cell comprises a pair of electrodes separated by a dielectric material and passageway therebetween. The electrochemical cell comprises a mixed-conducting solid oxide electrolyte membrane tube positioned between a porous cathode and a porous anode, and a gas inlet tube for feeding oxygen containing gas to the porous cathode. An inlet is provided for feeding hydrocarbons to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a light source for directing ultraviolet light into the discharge plasma cell and the electrochemical cell.

Claims18

Dependent claims

A method for direct conversion of hydrocarbons, the method comprising:

directing a hydrocarbon feed through a dielectric barrier discharge plasma to produce reactive hydrocarbon species;
subjecting the reactive hydrocarbon species to ultra-violet light;
passing an oxygen containing gas through a mixed-conducting solid oxide electrolyte membrane tube, having a porous anode on an exterior surface thereof and a porous cathode on an interior surface opposite from the porous anode, to thereby produce reactive oxygen-containing species;
reacting the hydrocarbon species with the oxygen-containing species to produce liquid products comprising fuel-type hydrocarbons and oxygenated hydrocarbons.

1 more element

Dependencies are inferred from the claim text.

Method for direct conversion of gaseous hydrocarbons to liquids

Life of this patent

Method for direct conversion of gaseous hydrocarbons to liquids

Life of this patent

Abstract

Claims18