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US 7,008,593 B2Granted
Deodorization of cationic acetonitrile derivatives
AssigneeHenkel Kommanditgesellschaft auf Aktien
InventorsGeorg Assmann, Horst-Dieter Speckmann, Wolfgang Lahn, Michael Lusse, Joerg Poethkow, Birgit Middelhauve, Gerhard Blasey, Helga Werner
Life of this patent
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Abstract
A process of deodorizing water-containing solutions of cationic nitrile bleach activators by exposure to the action of a combination of a percarboxylic acid, a carboxylic acid and hydrogen peroxide.
Claims13
A process of deodorizing water-containing solutions of compounds of the general formula I,
- where R1 is H, CH3, a C2-24-alkyl or alkenyl radical, a substituted C2-24-alkyl or -alkenyl radical having at least one substituent from the group consisting of Cl, Br, OH, NH2, CN, an alkyl radical or an alkenylaryl radical having a C1-24-alkyl group, or a substituted alkyl or alkenylaryl radical having a C1-24-alkyl group and at least one further substituent on the aromatic ring, R2 and R3 independently of one another are selected from —CH2—CN, —CH3, —CH2—CH3, —CH2—CH2—CH3, —CH(CH3)—CH3, —CH2—OH, —CH2—CH2—OH, —CH(OH)—CH3, —CH2—CH2—CH2—OH, —CH2—CH(OH)—CH3, —CH(OH)—CH2—CH3, —(CH2—CH2—O)nH where n=1, 2, 3, 4, 5 or 6, R4 and R5 independently of one another have a meaning specified above for R1, R2 or R3, and X is an anion of equivalent charge, by exposure to the action of an aqueous combination of a percarboxylic acid, a carboxylic acid and hydrogen peroxide, wherein the aqueous combination comprises 30% to 80% by weight of water.
A process of the deodorizing water-containing solutions of compounds of the general formula I,
- where R1 is H, CH3, a C2-24-alkyl or alkenyl radical, a substituted C2-24-alkyl or -alkenyl radical having at least one substituent from the group consisting of Cl, Br, OH, NH2, CN, an alkyl radical or an alkenylaryl radical having a C1-24-alkyl group, or a substituted alkyl or alkenylaryl radical having a C1-24-alkyl group and at least one further substituent on the aromatic ring, R2 and R3 independently of one another are selected from —CH2—CN, —CH3, —CH2—CH3, —CH2—CH2—CH3, —CH(CH3)—CH3, —CH2—OH, —CH2—CH2—OH, —CH(OH)—CH3, —CH2—CH2—CH2—OH, —CH2—CH(OH)—CH3, —CH(OH)—CH2—CH3, —(CH2—CH2—O)nH where n=1, 2, 3, 4, 5 or 6, R4 and R5 independently of one another have a meaning specified above for R1, R2 or R3, and X is an anion of equivalent charge, by exposure to the action of an aqueous combination of a percarboxylic acid, a carroxylic acid and hydrogen peroxide, wherein the aqueous deodorizing combination flas a carboxylic acid concentration of from 15% by weight to 60% by weight.
Dependencies are inferred from the claim text.