Water-absorbing polymers with supramolecular hollow molecules, method for producing them and use of the same
AssigneeStockhausen GmbH & Co. KG
InventorsChristoph Bruhn, Edgar Herrmann, Jörg Issberner, Dagmar Kersten, Richard Mertens, Georg Werner
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Abstract
The invention relates to absorbent polymers based on optionally partially neutralised, monoethylenically unsaturated, acid group-carrying monomers. The surfaces of said polymers are re-cross-linked. The inventive polymers also have cyclodextrines and/or cyclodextrine derivatives which are covalently and/or ionically bonded and/or included therein.
Claims31
A sheet material comprising absorptive polymer particles comprising one or more polymers comprising polymerized units of one or more monoethylenically unsaturated monomers having at least one acid group,
- wherein the surface of the absorptive polymer particles is secondary surface crosslinked, and
- wherein the polymer is at least partially neutralized and has one or more cyclodextrins, cyclodextrin derivatives, or both cyclodextrins and cyclodextrin derivatives, bonded covalently thereto, bonded ionically thereto, incorporated therein or a combination thereof.
Polymers based on crosslinked monomers bearing partially neutralized acid groups, the surface of which has been surface crosslinked folling polymerization, obtained by a process wherein
- an aqueous solution containing partially neutralized acrylic acid is converted to a gel in the presence of crosslinkers and optional polymer additives;
- the gel is subsequently dried, milled and screened to the desired particle size;
- the polymer is surface cross-linked before or after the gel has been dried wherein cyclodextrines or derivatives thereof as a substance or dissolved in a solvent
- are added directly to the aqueous monomer solution prior to the polymerization thereof;
- are applied to a non-dried polymer gel;
- are added onto the crushed and dried absorbent material during surface corsslinking of the polymer product;
- are applied onto the crushed, already surface crosslinked polymer product.
A polymer comprising polymerized units of one or more monomers having at least partially neutralized acid groups, wherein the polymer is a crosslinked polymer obtained by
- polymerizing an aqueous solution comprising at least partially neutralized acrylic acid and one or more crosslinkers, to form a gel,
- drying the gel,
- milling and screening the dried gel,
- adding one or more cyclodextrins or derivatives thereof as a solid or as a solution in a solvent, and
- surface crosslinking the gel.
The polymer of claim 41, wherein the cyclodextrins or derivatives thereof are added to the dried, milled and screened gel after crosslinking.
Dependencies are inferred from the claim text.