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US 6,888,020 B2Granted
Water-soluble dithioesters and method for polymerization thereof
AssigneeLG Chem, Ltd.
InventorsHee-Jung Kim, Dong-Ryul Kim
Life of this patent
Estimating the term…
Abstract
Disclosed are water soluble dithioesters capable of acting as chain transfer agents in preparing a vinyl-based polymer to control molecular weight and molecular weight distribution thereof as well as being capable of living polymerization even in an aqueous solution, and a method for polymerization thereof.
Claims3
A water soluble dithioester compound represented by the following Chemical Formula 1:
- in the Chemical Formula 1,
- Z is a hydrogen, a chlorine;
- or an alkyl, an aryl, an alkylthio, an alkoxycarbonyl, an aryoxycarbonyl (—COOR″), an carboxy (—COOH), an acyloxy (—O2CR″), a cabamoyl (—CONR″), a cyano (—CN), a dialkyl-phosphonato, a diaryl-phosphonato (—P(═O)OR″2), a dialkyl-phosphinato, or a diaryl-phosphinato (—P(═O)R″2) unsubstituted or substituted which substitutents,
- R″ is C1-18 alkyl, C2-18 alkenyl, aryl, heterocyclyl, aralkyl, or alkylaryl unsubstituted or substituted with a substitutent selected from the group consisting of epoxy, alkoxycarbonyl, aryloxycarbonyl, isocyanto, cyano, silyl, halo, and dialkylamino,
- R1 is C1-18 alkyl, C2-18 alkenyl, aryl, heterocyclyl, aralkyl, or alkylaryl unsubstituted or substituted with a substitutent selected from the group consisting of hydrogen, ester, keto, amide, ether, thio, hydroxy, cyano, silyl, halo, and dialkylamino, and
- R2 and R3 are independently C1-18 alkyl, C2-18 alkenyl, aryl, heterocyclyl, aralkyl, or alkylaryl unsubstituted or substituted with a substitutent selected from the group consisting of ester, keto, amide, ether, thio, hydroxy, cyano, silyl, halo, and dialkylamino, and at least one of R2 and R3 contains an ammonium salt represented by the Chemical Formula 2 having a cationic substitutent at its end or a hetero ring salt unsubstituted or substituted with substitutents represent by the Chemical Formula 3:
- in the Chemical Formula 2,
- R4, R5, and R6 are independently an alkyl which contains branched, normal saturated or unsaturated, alkyl which contain aryl substitutent, alkoxyalkyl, cyanoalkyl, or hydroxyalkyl,
- X is a halide or a sulfate,
- in the Chemical Formula 3,
- a hetero ring of hetero ring salt is heterocyclic moiety having 5 or 6 membered rings, and can contain independently alkyl, or alkene,
- Q is a halide or a sulfate.
9 more elements
A chain transfer agent for preparing a vinyl-based polymer comprising a water soluble dithioester compound represented by the following Chemical Formula 1:
- in the Chemical Formula 1,
- Z is a hydrogen, a chlorine;
- or an alkyl, an aryl, an alkylthio, an alkoxycarbonyl, an aryoxycarbonyl (—COOR″), an carboxy (—COOH), an acyloxy (—O2CR″), a cabamoyl (—CONR″), a cyano (—CN), a dialkyl-phosphonato, a diaryl-phosphonato (—P(═O)OR″2), a dialkyl-phosphinato, or a diaryl-phosphinato (—P(═O)R″2) unsubstituted or substituted which substitutents,
- R″ is C1-18 alkyl, C2-18 alkenyl, aryl, heterocyclyl, aralkyl, or alkylaryl unsubstituted or substituted with a substitutent selected from the group consisting of epoxy, alkoxycarbonyl, aryloxycarbonyl, isocyanto, cyano, silyl, halo, and dialkylamino,
- R1 is C1-18 alkyl, C2-18 alkenyl, aryl, heterocyclyl, aralkyl, or alkylaryl unsubstituted or substituted with a substitutent selected from the group consisting of hydrogen, ester, keto, amide, ether, thio, hydroxy, cyano, silyl, halo, and dialkylamino, and
- R2 and R3 are independently C1-18 alkyl, C2-18 alkenyl, aryl, heterocyclyl, aralkyl, or alkylaryl unsubstituted or substituted with a substitutent selected from the group consisting of ester, keto, amide, ether, thio, hydroxy, cyano, silyl, halo, and dialkylamino, and at least one of R2 and R3 contains an ammonium salt represented by the Chemical Formula 2 having a cationic substitutent at its end or a hetero ring salt unsubstituted or substituted with substitutents represent by the Chemical Formula 3:
- in the Chemical Formula 2,
- R4, R5, and R6 are independently an alkyl which contains branched, normal saturated or unsaturated, alkyl which contain aryl substitutent, alkoxyalkyl, cyanoalkyl, or hydroxyalkyl,
- X is a halide or a sulfate,
- in the Chemical Formula 3,
- a hetero ring of the hetero ring salt is heterocyclic moiety having 5 or 6 membered rings, and can contain independently alkyl, or alkene,
- Q is a halide or a sulfate.
9 more elements
Dependencies are inferred from the claim text.