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AssigneesSumitomo Metal Industries, Ltd., Matsushita Electric Industrial Co., Ltd.
InventorsHideya Kaminaka, Masaru Abe, Noriyuki Negi, Yoshiaki Nitta, Harunari Shimamura, Kazuhiro Okamura
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A negative electrode material for a nonaqueous electrolyte secondary battery having a high discharge capacity and a good cycle life is made from alloy particles having an average particle diameter of 0.1-50 μm and including Si phase grains 40 and a phase of a solid solution or an intermetallic compound of Si and other element selected from Group 2A elements, transition elements, Group 3B elements, and Group 4B elements from the long form periodic table (for example, an NiSi2 phase 42 and an [NiSi2+NiSi] phase 41) at least partially enveloping the Si phase grains. 5-99 wt % of this material is Si phase grains. The alloy particles can be manufactured by rapid solidification (such as atomization or roller quenching) of a melt including Si and the other element, or by adhering the other element to Si powder by electroless plating or mechanical alloying and then performing heat treatment. Even if rapid solidification is carried out, a negative electrode material having a good discharge capacity and cycle life is obtained without heat treatment.
A process for manufacturing a negative electrode material for a nonaqueous electrolyte secondary battery, which is made from alloy particles of a structure comprising one or more Si phase grains at least partially enveloped in a phase consisting essentially of an Si-containing solid solution or Si-containing intermetallic compound, the process comprising solidifying a melt of raw materials for the alloy particles by cooling so as to obtain a cooling rate of at least 100° C. per second and forming said alloy particles of a structure comprising one or more Si phase grains at least partially enveloped in a phase of a Si-containing solid solution or Si-containing intermetallic compound.
A process for manufacturing a negative electrode material for a nonaqueous electrolyte secondary battery, which is made from alloy particles of a structure comprising one or more Si phase grains at least partially enveloped in a phase consisting essentially of an Si-containing solid solution or Si-containing intermetallic compound, the process comprising forming an adhering layer of a material by a mechanical alloying method which contains an element capable of forming a solid solution or an intermetallic compound with Si, on the surface of a powder of metallic Si or an alloy having an Si phase, and subjecting the powder having the adhering layer to heat treatment at a temperature at least 10° C. below the solidus temperature of the solid solution or the intermetallic compound to convert the material forming the adhering layer to form an Si-containing solid solution or Si-containing intermetallic compound.
A process of manufacturing a negative electrode for a nonaqueous electrolyte secondary battery, comprising adhering a powder of metallic Si or of an alloy containing an Si phase on a negative electrode substrate to form a powder layer on the substrate, plating the powder layer with a material comprising an element capable of forming a solid solution or intermetallic compound with Si, and thereafter performing heat treatment at a temperature at least 10° C. below the solidus temperature of the solid solution or intermetallic compound so as to convert the plating to form an Si-containing solid solution or Si-containing intermetallic compound.
Dependencies are inferred from the claim text.