Monodisperse particles, process for producing the same, and uses thereof

A process for producing monodisperse particles which comprises:

• a) a step of mixing a polymerizable monomer, an oil-soluble polymerization initiator, a non-aqueous organic solvent and water to form an aqueous emulsion;
• b) a step of adding an aqueous dispersion of monodisperse polymer seed particles to the aqueous emulsion obtained in step a) to thereby swell the polymer seed particles;
• and
• c) a step of polymerizing the polymerizable monomers in the swollen polymer seed particles,
• wherein
• d) the polymer seed particles are monodisperse seed particles having a weight average molecular weight of 50,000 or lower, consisting of a poly(meth)acrylic ester) containing at least one substituent selected from the group consisting of straight-chain alkyl groups having 6 or more carbon atoms, alicyclic alkyl groups having 6 or more carbon atoms, phenyl groups, benzyl groups and halogenated alkyl groups having 3 or more carbon atoms;
• e) the monodisperse particles obtained in the polymerization step c) are formed such that the polymer seed particles and the polymer obtained by polymerizing the polymerizable monomers do not cause phase separation;
• f) the amount of the polymerizable monomer and the non-aqueous organic solvent is 10 to 50,000 times by volume of the polymer seed particles;
• g) the non-aqueous organic solvent is a higher alcohol selected from the group consisting of butanol, pentanol and hexanol;
• and
• h) the non-aqueous organic solvent is added in an amount of 102 to 200 parts by weight per 100 parts by weight of the polymerizable monomer.