Golf balls comprising light stable materials and methods of making the same
AssigneeAcushnet Company
InventorsShenshen Wu, Craig A. Wilson, Murali Rajagopalan
Life of this patent
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Abstract
Golf equipment having improved cut and shear resistance that includes a polyurea composition, preferably saturated, formed of a polyurea prepolymer and a curing agent, wherein the polyurea prepolymer includes an isocyanate and a polyether amine, and wherein the curing agent includes a hydroxy-terminated curing agent, amine-terminated curing agent, or a mixture thereof.
Claims27
A golf ball comprising at least one light stable cover layer formed from a polyurea composition consisting of a prepolymer and an amine-terminated curing agent, wherein the prepolymer is the reaction product of a diisocyanate selected from the group consisting of ethylene diisocyanate;
- propylene-1,2-diisocyanate;
- tetramethylene diisocyanate;
- tetramethylene-1,4-diisocyanate;
- 1,6-hexamethylene-diisocyanate;
- octamethylene diisocyanate;
- decamethylene diisocyanate;
- 2,2,4-trimethylhexamethylene diisocyanate;
- 2,4,4-trimethylhexamethylene diisocyanate;
- dodecane-1,12-diisocyanate;
- dicyclohexylmethane diisocyanate;
- cyclobutane-1,3-diisocyanate;
- cyclohexane-1,2-diisocyanate;
- cyclohexane-1,3-diisocyanate;
- cyclohexane-1,4-diisocyanate;
- methyl-cyclohexylene diisocyanate;
- 2,4-methylcyclohexane diisocyanate;
- 2,6-methylcyclohexane diisocyanate;
- 4,4′-dicyclohexyl diisocyanate;
- 2,4′-dicyclohexyl diisocyanate;
- 1,3,5-cyclohexane triisocyanate;
- isocyanatomethylcyclohexane isocyanate;
- 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethylcyclohexane;
- isocyanatoethylcyclohexane isocyanate;
- bis(isocyanatomethyl)-cyclohexane diisocyanate;
- 4,4′-bis(isocyanatomethyl)dicyclohexane;
- 2,4′-bis(isocyanatomethyl)dicyclohexane;
- isophoronediisocyanate;
- triisocyanate of HDI;
- triisocyanate of 2,2,4-trimethyl-1,6-hexane diisocyanate;
- 4,4′-dicyclohexylmethane diisocyanate;
- 2,4-hexahydrotoluene diisocyanate;
- 2,6-hexahydrotoluene diisocyanate;
- and mixtures thereof and a polyether amine selected from the group consisting of polytetramethylene ether diamines, polyoxypropylene diamines, poly(ethylene oxide capped oxypropylene) ether diamines, triethyleneglycoldiamines, propylene oxide-based triamines, trimethylolpropane-based triamines, glycerin-based triamines, and mixtures thereof.
A golf ball comprising:
- a core;
- a layer disposed about the core forming a center;
- and
- a cover cast onto the center, wherein the cover comprises a light stable polyurea material consisting essentially of a diisocyanate selected from the group consisting of ethylene diisocyanate;
- propylene-1,2-diisocyanate;
- tetramethylene diisocyanate;
- tetramethylene-1,4-diisocyanate;
- 1,6-hexamethylene-diisocyanate;
- octamethylene diisocyanate;
- decamethylene diisocyanate;
- 2,2,4-trimethylhexamethylene diisocyanate;
- 2,4,4-trimethylhexamethylene diisocyanate;
- dodecane-1,12-diisocyanate;
- dicyclohexylmethane diisocyanate;
- cyclobutane-1,3-diisocyanate;
- cyclohexane-1,2-diisocyanate;
- cyclohexane-1,3-diisocyanate;
- cyclohexane-1,4-diisocyanate;
- methyl-cyclohexylene diisocyanate;
- 2,4-methylcyclohexane diisocyanate;
- 2,6-methylcyclohexane diisocyanate;
- 4,4′-dicyclohexyl diisocyanate;
- 2,4′-dicyclohexyl diisocyanate;
- 1,3,5-cyclohexane triisocyanate;
- isocyanatomethylcyclohexane isocyanate;
- 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethylcyclohexane;
- isocyanatoethylcyclohexane isocyanate;
- bis(isocyanatomethyl)-cyclohexane diisocyanate;
- 4,4′-bis(isocyanatomethyl)dicyclohexane;
- 2,4′-bis(isocyanatomethyl)dicyclohexane;
- isophoronediisocyanate;
- triisocyanate of HDI;
- triisocyanate of 2,2,4-trimethyl-1,6-hexane diisocyanate;
- 4,4′-dicyclohexylmethane diisocyanate;
- 2,4-hexahydrotoluene diisocyanate;
- 2,6-hexahydrotoluene diisocyanate;
- and mixtures thereof, a polyether amine selected from the group consisting of polytetramethylene ether diamines, polyoxypropylene diamines, poly(ethylene oxide capped oxypropylene) ether diamines, triethyleneglycoldiamines, propylene oxide-based triamines, trimethyloipropane-based triamines, glycerin-based triamines, and mixtures thereof, and an amine-terminated curing agent.
A golf ball comprising a cover layer formed from a polyurea composition consisting essentially of:
- a polyurea prepolymer formed from the reaction product of;
- an isocyanate having the structure O═C═N—R—N═C═O, wherein R consists of a cyclic, aromatic, or linear or branched hydrocarbon moiety containing from about 1 to about 20 carbon atoms;
- and
- a polyether amine selected from the group consisting of
- wherein the repeating unit x has a value ranging from about 1 to about 70,
- wherein x and z have combined values from about 3.6 to about 8, y ranges from about 9 to about 50, and wherein R is —(CH2)a— and a ranges from about 1 to about 10,
- H2N—(R)—O—(R)—O—(R)—NH2
- wherein R is —(CH2)a and a ranges from about 1 to about 10, and mixtures thereof;
- and
- an amine-terminated curing agent.
Dependencies are inferred from the claim text.