Organic EL device and preparation method
AssigneeTDK Corporation
InventorsEmiko Kambe, Masahiro Shinkai
Life of this patent
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Abstract
In an organic EL device comprising a cathode, an anode, and two or more stacked organic layers therebetween including a light emitting layer, an electron injecting organic layer containing an organic salt or complex of a metal having a standard electrode potential of more negative than −1.8 V at 25° C. is formed close to the cathode by coating, and an organic layer containing a high molecular weight EL material is disposed close to the electron injecting organic layer. A multilayer structure of organic layers can be formed by coating, and the organic EL device has a high luminance, high efficiency, high reliability, long life and ease of handling.
Claims14
An organic EL device comprising a cathode, an anode, and two or more stacked organic layers therebetween including a light emitting layer, at least two organic layers being formed by coating, wherein
- the organic layer disposed contiguous to the cathode is an electron injecting organic layer containing at least one compound selected from organic metal salts and organic metal complexes of a metal having a standard electrode potential of more negative than −1.8 V at 25° C., and formed by coating, and
- an organic layer containing a high molecular weight EL material is disposed contiguous to the electron injecting organic layer on the cathode side, and formed by coating,
- wherein the electron injecting organic layer is formed by coating a solution of the at least one compound in a solvent which is selected from the group consisting of (i) a chain compound of 3 to 6 carbon atoms in total, having on the molecule at least one alkoxy group of 1 to 3 carbon atoms, carbonyl group, or ester group of 2 to 3 carbon atoms, and a hydroxyl group at the α- and/or β-position thereto, (ii) a chain compound of 3 to 6 carbon atoms in total, having on the molecule a dialkylamide group of 2 to 4 carbon atoms, (iii) an ester form of chain compound having 5 to 8 carbon atoms in total, (iv) a carbonate form of chain compound having 4 to 7 carbon atoms in total, and (v) mixtures thereof.
An organic EL device comprising, in order, a substrate, a first electrode on the substrate, two or more stacked organic layers on the first electrode including a light emitting layer, and a second electrode on the organic layers, wherein
- at least one layer of the two or more stacked organic layers other than the light emitting layer contains at least one high or low molecular weight compound selected from the group consisting of oxadiazole, triazole, thiadiazole, quinoline, quinoxaline, phenanthroline, and derivatives thereof,
- the light emitting layer contains a polymer which is a π-conjugated polymer, polyvinyl compound, polyacrylate, polymethacrylate or a derivative thereof, and
- the organic layers are formed by coating,
- wherein the at least one layer containing at least one high or low molecular weight compound is formed by coating a solution of the at least one high or low molecular weight compound in a solvent which is selected from the group consisting of (i) a chain compound of 3 to 6 carbon atoms in total, having on the molecule at least one alkoxy group of 1 to 3 carbon atoms, carbonyl group, or ester group of 2 to 3 carbon atoms, and a hydroxyl group at the α- and/or β-position thereto, (ii) a chain compound of 3 to 6 carbon atoms in total, having on the molecule a dialkylamide group of 2 to 4 carbon atoms, (iii) an ester form of chain compound having 5 to 8 carbon atoms in total, (iv) a carbonate form of chain compound having 4 to 7 carbon atoms in total, and (v) mixtures thereof.
An organic EL device according to claim 21 wherein the polymer in the light emitting layer is selected from the group consisting of polyfluorene and derivatives thereof, poly(p-phenylene vinylene) and derivatives thereof, poly(biphenylene vinylene) and derivatives thereof, poly(terphenylene vinylene) and derivatives thereof, poly(naphthylene vinylene) and derivatives thereof, poly(thienylene vinylene) and derivatives thereof, polythiophene and derivatives thereof, polyvinyl compounds, polyacrylate derivatives, and polymethacrylate derivatives.
Dependencies are inferred from the claim text.