A method of measuring the deposit amount of a metal phase contained in a galvanized layer by using X-ray diffractometry, the method comprising measuring diffracted X-rays from the metal phase contained in the galvanized layer over a predetermined range on a Debye ring, and integrating the obtained X-ray diffraction intensity data, wherein, prior to the step of measuring the diffracted X-rays, the method comprises a further step of limiting the diffracted X-rays being measured to those diffracted X-rays passing through a slit corresponding to a portion of a circumference of the Debye ring.