Pattern formation material and pattern formation method
AssigneeMatsushita Electric Industrial Co., Ltd.
InventorsShinji Kishimura, Masayuki Endo, Masaru Sasago, Mitsuru Ueda, Tsuyohiko Fujigaya
Life of this patent
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Abstract
A pattern formation material of this invention contains a base polymer including a first unit represented by Chemical Formula 1 and a second unit represented by Chemical Formula 2, and an acid generator: wherein R1 and R2 are the same or different and selected from the group consisting of a hydrogen atom, a chlorine atom, a fluorine atom, an alkyl group and an alkyl group including a fluorine atom; R3 is a protecting group released by an acid; m is an integer of 0 through 5; and a and b satisfy 0<a<1,0<b<1 and 0<a+b≦1.
Claims28
A pattern formation material comprising:
- a base polymer including a first unit represented by Chemical Formula 1 and a second unit represented by Chemical Formula 2;
- and an acid generator:
- wherein R1 and R2 are the same or different and selected from the group consisting of a hydrogen atom, a chlorine atom, a fluorine atom, an alkyl group and an alkyl group including a fluorine atom;
- R3 is a protecting group released by an acid;
- m is an integer of 0 through 5;
- and a and b satisfy 0<a<1,0<b<1 and 0<a+b≦1.
A pattern formation material comprising:
- a base polymer including a first unit represented by Chemical Formula 1, a second unit represented by Chemical Formula 2 and a third unit represented by Chemical Formula 3;
- and an acid generator:
- wherein R1, R2 and R4 are the same or different and selected from the group consisting of a hydrogen atom, a chlorine atom, a fluorine atom, an alkyl group and an alkyl group including a fluorine atom;
- R3 is a protecting group released by an acid;
- m and n are integers of 0 through 5;
- and a, b and c satisfy 0<a<1,0<b<1,0<c<1 and 0<a+b+c≦1.
A pattern formation material comprising:
- a base polymer including a first unit represented by Chemical Formula 1 and a second unit represented by Chemical Formula 4;
- and an acid generator:
- wherein R1 is a hydrogen atom, a chlorine atom, a fluorine atom, an alkyl group or an alkyl group including a fluorine atom;
- R5 is a protecting group released by an acid;
- p is an integer of 0 through 5;
- and a and d satisfy 0<a<1,0<d<1 and 0<a+d≦1.
A pattern formation material comprising:
- a base polymer including a first unit represented by Chemical Formula 1, a second unit represented by Chemical Formula 4 and a third unit represented by Chemical Formula 5;
- and an acid generator:
- wherein R1 is a hydrogen atom, a chlorine atom, a fluorine atom, an alkyl group or an alkyl group including a fluorine atom;
- R5 is a protecting group released by an acid;
- p and q are integers of 0 through 5;
- and a, d and e satisfy 0<a<1,0<d<1,0<e<1 and 0<a+d+e≦1.
A pattern formation method comprising the steps of:
- forming a resist film by applying, on a substrate, a pattern formation material containing a base polymer including a first unit represented by Chemical Formula 1 and a second unit represented by Chemical Formula 2, and an acid generator:
- wherein R1 and R2 are the same or different and selected from the group consisting of a hydrogen atom, a chlorine atom, a fluorine atom, an alkyl group and an alkyl group including a fluorine atom;
- R3 is a protecting group released by an acid;
- m is an integer of 0 through 5;
- and a and b satisfy 0<a<1,0<b<1 and 0<a+b≦1;
- irradiating said resist film with exposing light of a wavelength not longer than a 180 nm band for pattern exposure;
- and
- forming a resist pattern by developing said resist film after the pattern exposure.
A pattern formation method comprising the steps of:
- forming a resist film by applying, on a substrate, a pattern formation material containing a base polymer including a first unit represented by Chemical Formula 1, a second unit represented by Chemical Formula 2 and a third unit represented by Chemical Formula 3, and an acid generator;
- wherein R1, R2 and R4 are the same or different and selected from the group consisting of a hydrogen atom, a chlorine atom, a fluorine atom, an alkyl group and an alkyl group including a fluorine atom;
- R3 is a protecting group released by an acid;
- m and n are integers of 0 through 5;
- and a, b and c satisfy 0<a<1,0<b<1,0<c<1 and 0<a+b+c≦1;
- irradiating said resist film with exposing light of a wavelength not longer than a 180 nm band for pattern exposure;
- and
- forming a resist pattern by developing said resist film after the pattern exposure.
A pattern formation method comprising the steps of:
- forming a resist film by applying, on a substrate, a pattern formation material containing a base polymer including a first unit represented by Chemical Formula 1 and a second unit represented by Chemical Formula 4, and an acid generator:
- wherein R1 is a hydrogen atom, a chlorine atom, a fluorine atom, an alkyl group or an alkyl group including a fluorine atom;
- R5 is a protecting group released by an acid;
- p is an integer of 0 through 5;
- and a and d satisfy 0<a<1,0<d<1 and 0<a+d≦1;
- irradiating said resist film with exposing light of a wavelength not longer than a 180 nm band for pattern exposure;
- and
- forming a resist pattern by developing said resist film after the pattern exposure.
A pattern formation method comprising the steps of:
- forming a resist film by applying, on a substrate, a pattern formation material containing a base polymer including a first unit represented by Chemical Formula 1, a second unit represented by Chemical Formula 4 and a third unit represented by Chemical Formula 5, and an acid generator:
- wherein R1 is a hydrogen atom, a chlorine atom, a fluorine atom, an alkyl group or an alkyl group including a fluorine atom;
- R5 is a protecting group released by an acid;
- p and q are integers of 0 through 5;
- and a, d and e satisfy 0<a<1,0<d<1,0<e<1 and 0<a+d+e≦1;
- irradiating said resist film with exposing light of a wavelength not longer than a 180 nm band for pattern exposure;
- and
- forming a resist pattern by developing said resist film after the pattern exposure.
Dependencies are inferred from the claim text.