Hot melt inks containing styrene or terpene polymers
AssigneeXerox Corporation
InventorShadi L. Malhotra
Life of this patent
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Abstract
Disclosed is an ink composition comprising (a) a styrene polymer or terpene polymer hardening component, (b) a nonpolymeric aromatic viscosity modifier, (c) a colorant, (d) an optional nonpolymeric aromatic ink vehicle, (e) an optional colorant dispersing agent, (f) an optional conductivity enhancing agent, (g) an optional antioxidant, and (h) an optional UV absorber.
Claims35
A hot melt ink composition comprising (a) a terpene polymer hardening component, (b) a nonpolymeric aromatic viscosity modifier, (c) a colorant, (d) an optional nonpolymeric aromatic ink vehicle, (e) an optional colorant dispersing agent, (f) an optional conductivity enhancing agent, (g) an optional antioxidant, and h) an optional UV absorber.
A printing process which comprises incorporating into an ink jet printing apparatus a hot melt ink composition comprising (a) a styrene polymer or terpene polymer hardening component, (b) a nonpolymeric aromatic viscosity modifier which is a biphenyl compound, a fluorine compound, a phenanthrene compound, a pyrene compound, an adamantine compound, a dibenzo compound, a diphenyl phosphino compound, a phenylsulfonyl compound, or mixtures thereof, (c) a colorant, (d) an optional nonpolymeric aromatic ink vehicle, (e) an optional colorant dispersing agent, (f) an optional conductivity enhancing agent, (g) an optional antioxidant, and (h) an optional UV absorber, melting the ink, and causing droplets of the melted ink to be ejected in an imagewise pattern onto a recording sheet.
A hot melt ink composition comprising (a) a hardening component which comprises poly(α-methyl styrene), poly(methyl styrene-co-indene) hydrogenated, poly(styrene-co-allyl alcohol), or a mixture thereof, (b) a nonpolymeric aromatic viscosity modifier, (c) a colorant, (d) an optional nonpolymeric aromatic ink vehicle, (e) an optional colorant dispersing agent, (f) an optional conductivity enhancing agent, (g) an optional antioxidant, and (h) an optional UV absorber.
A hot melt ink composition comprising (a) a styrene polymer or terpene polymer hardening component, (b) a nonpolymeric aromatic viscosity modifier, (c) a colorant, (d) an optional nonpolymeric aromatic ink vehicle, (e) an optional colorant dispersing agent, (f) an optional conductivity enhancing agent, (g) an optional antioxidant, and (h) an optional UV absorber, wherein the ink exhibits an acoustic-loss value of no more than about 100 decibels per millimeter.
A hot melt ink composition comprising (a) a styrene polymer or terpene polymer hardening component, (b) a nonpolymeric aromatic viscosity modifier, (c) a colorant, (d) an optional nonpolymeric aromatic ink vehicle, (e) an optional colorant dispersing agent, (f) an optional conductivity enhancing agent, (g) an optional antioxidant, and (h) an optional UV absorber, wherein the ink exhibits a conductivity of no less than about 6 log(picomho/cm).
A hot melt ink composition comprising (a) a styrene polymer or terpene polymer hardening component, (b) a nonpolymeric aromatic viscosity modifier, (c) a colorant, (d) an optional nonpolymeric aromatic ink vehicle, (e) an optional colorant dispersing agent, (f) an optional conductivity enhancing agent, (g) an optional antioxidant, and (h) an optional UV absorber, wherein images generated with the ink exhibit a haze value of no more than about 25.
A hot melt ink composition comprising (a) a styrene polymer or terpene polymer hardening component, (b) a nonpolymeric aromatic viscosity modifier, (c) a colorant, (d) an optional nonpolymeric aromatic ink vehicle, (e) an optional colorant dispersing agent, (f) an optional conductivity enhancing agent (g) an optional antioxidant, and (h) an optional UV absorber, wherein the viscosity modifier is a biphenyl compound, a fluorene compound, a phenanthrene compound, a pyrene compound, an adamantane compound, a dibenzo compound, a diphenylphosphino compound, a phenylsulfonyl compound, or mixtures thereof.
A hot melt ink composition comprising (a) a styrene polymer or terpene polymer hardening component, (b) a nonpolymeric aromatic viscosity modifier, (c) a colorant, (d) an optional nonpolymeric aromatic ink vehicle, (e) an optional colorant dispersing agent, (f) an optional conductivity enhancing agent, (g) an optional antioxidant, and (h) an optional UV absorber, wherein the viscosity modifier is biphenylene, 4-acetylbiphenyl, 2-biphenyl carboxylic acid, 2,2′-biphenyldimethanol, 4,4′-dimethyl biphenyl, 2,2′-bis(bromomethyl)-1,1′-biphenyl, 4,4′-bis-(dimethylamino) biphenyl carbinol, 4-bromo biphenyl, diphenylfulvene, diphenyl sulfone, 1,2-diphenoxy ethane, triphenyl methane, fluorene, 9-fluorene methanol, 9-fluorene acetic acid, 3-amino fluoranthene, 1-amino fluorene, 2-amino fluorene, 9-bromo-9-phenylfluorene, 1-methyl fluorene, methyl-9-fluorenylidene acetate, 4,4′-(9-fluorenylidene) bis(2-phenoxy ethanol), N-(9-fluorenyl methoxy carbonyl)-valinol, 9-fluorenone, phenanthrene, 9-iodophenanthrene, 9-acetylphenanthrene, 9-amino phenanthrene, 1-amino pyrene, 1-acetylpyrene, 1-bromopyrene, 1-(bromoacetyl) pyrene, 1,2,3,6,7,8-hexa hydropyrene, 1-pyrenemethanol, 1-pyrenebutanol, 1-adamantane methanol, 1-adamantane ethanol, 1-bromo adamantane, 2-bromo adamantane, 1-iodo adamantane, 2-(1-adamantyl)-4-methyl phenol, 1-bromo-3-(bromomethyl) adamantane, 1-bromo-3,5-dimethyl adamantane, 3-(bromomethyl)-2,4,10-trioxa adamantane, 1,3-dibromoadamantane, 1,4-dibromoadamantane, dimethyl-1,3-adamantane dicarboxylate, 1-azido adamantane, 3-noradamantane carboxylic acid, 1-adamantyl bromomethyl ketone, dibenzo-24-crown-8, dibenzo-30-crown-10, dibenzofuran, dibenzosuberane, dibenzosuberenol, dibenzosuberol, dibenzosuberenone, dibenzothiophene, diphenylfulvene, 1,3-diphenyl isobenzofuran, bis(diphenylphosphino) methane, 1,2-bis(diphenylphosphino) ethane, 1,2-bis(diphenylphosphino) ethylene, 1,4-bis(diphenylphosphino) butane, 2,3-bis(diphenylphosphino) butane, 1,6-bis(diphenylphosphino) hexane, 1,1,1-tris(diphenylphosphino methyl) ethane, 1,4-bis(dicyclohexyl phosphino) butane, 1,2-bis(phenylsulfonyl) ethylene, bis(phenylsulfonyl) methane, 1-bromomethyl-2-((phenylsulfonyl) methyl) benzene, 2-(phenylsulfonyl)tetrahydropyran, or mixtures thereof.
A hot melt ink composition comprising (a) a styrene polymer or terpene polymer hardening component, (b) a nonpolymeric aromatic viscosity modifier, (c) a colorant, (d) a nonpolymeric aromatic ink vehicle, (e) an optional colorant dispersing agent, (f) an optional conductivity enhancing agent, (g) an optional antioxidant, and (h) an optional UV absorber, wherein the ink vehicle is 4-hexyl resorcinol, 4-dodecyl resorcinol, 4-(tert-octyl) phenol, 4-bromo-N-dodecyl-1-hydroxy-2-naphthalene carboxamide, 2,2-diphenyl-1,4-diazaspiro-(4,5-)deca-1,3-diene, N,N′-dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane, 1,4-dihydro-9-isopropylidene-1,4-methanonaphthalene, 1,4,4a,8a-otetrahydro-endo-1,4-methanonaphthalene, 1,5-dihydroxy-1,2,3,4-tetrahydronaphthalene, 2,5-difluorophenylhydrazine, or mixtures thereof.
A hot melt ink composition comprising (a) a styrene polymer or terpene polymer hardening component, (b) a nonpolymeric aromatic viscosity modifier, (c) a colorant, (d) an optional nonpolymeric aromatic ink vehicle, (e) a colorant dispersing agent, (f) an optional conductivity enhancing agent, (g) an optional antioxidant, and (h) an optional UV absorber, wherein the colorant dispersing agent is 2-hydroxyisocaproic acid, 2-hydroxy isobutyric acid, benzylmalonic acid, dibenzoyltartaric acid, methylsuccinic acid, 2-ethyl-2-methylsuccinic acid, 2,2-dimethyl glutaric acid, 3,3-dimethylglutaric acid, 1-hydroxy-1-cyclopropane carboxylic acid, 2,2,3,3-tetramethyl cyclopropane carboxylic acid, 1-benzo cyclobutane carboxylic acid, 3-oxo-1-indan carboxylic acid, 2-oxo-6-pentyl-2H-pyran-3-carboxylic acid, diphenyl carbonate, 1,2-diphenylvinylene carbonate, 2-oxazolidone, flavone, 4-methoxy chalcone, 4′-methoxy chalcone, γ-(2-naphthyl)-γ-butyrolactone, diphenyl-γ-butyrolactone, 2,6-dimethyl-4H-pyran-4-one, distyryl ketone, 4-(4-hydroxyphenyl)-2-butanone, 1,3-dacetyl-2-imidazolidinone, 2,6-diphenyl cyclohexanone, flavanone, 1-(2-hydroxyphenyl)-3-phenyl-1,3-propanedione, 1-(2-hydroxy-5-methylphenyl)-3-phenyl-1,3-propanedione, tetramethyl-1,3-cyclobutanedione, 2,5-oxazolidinedione, 5,5-dimethyloxazolidine-2,4-dione, 3,6-dimethyl-1,4-dioxane-2,5-dione, 2,2-dimethyl-1,3-dioxane-4,6-dione, 4,4-dimethyl-1,3-cyclohexanedione, benzlphenyl ketone, di-n-benzyl ketone, diphenyl acetone, poly(vinyl phenyl ketone), poly(vinyl phenyl ketone) hydrogenated, polycyclohexanone, poly(coumarone-co-indene), polycaprolactone, poly(ethelene-co-carbon monoxide), poly(1-vinylpyrollidone)-graft-(1-triacontene), 3-hydroxybenzaldehyde, 4-hydroxybenzaldehyde, 4-benzyloxybenzaldehyde, 2-carboxybenzaldehyde, 4-nitrobenzaldehyde, 2,3-dihydroxybenzaldehyde, 2,5-dihydroxybenzaldehyde, 3-hydroxy-4-methoxybenzaldehyde, 4-hydroxy-3-methoxybenzaldehyde, 4-hydroxy-3-ethoxybenzaldehyde, 4-hydroxy-3-methylbenzaldehyde, 2-hydroxy-5-nitrobenzaldehyde, 3-hydroxy-4-nitrobenzaldehyde, 4-hydroxy-3-nitrobenzaldehyde, 3,4-dibenzyloxy benzaldehyde, 3,5-dibenzyloxybenzaldehyde, 4-acetoxy-3,5-dimethoxybenzaldehyde, 2-amino-3,5-dibromobenzaldehyde, 2-benzyloxy-4,5-dimethoxybenzaldehyde, 5-bromo-2-hydroxy-3-methoxybenzaldehyde, 4-hydroxy-3,5-dimethoxybenzaldehyde, 2,3,5-trichlorobenzaldehyde, 2,3,6-trichlorobenzaldehyde, 2,4,5-trimethoxybenzaldehyde, 2,4,6-trimethoxybenzaldehyde, 3,5-dichloro-2-hydroxybenzaldehyde, 3,5-dibromo-2-hydroxybenzaldehyde, 3,5-diiodo-2-hydroxybenzoldehyde, 3,4-dihydroxy-5-methoxybenzaldehyde, 3,5-dimethyl-4-hydroxybenzaldehyde, 2,6-dimethoxybenzaldehyde, trans-2-nitro cinnamaldehyde, trans-4-(diethylamino) cinnamaldehyde, 4-acetoxy-3-methoxy cinnamaldehyde, 4-hydroxy-3-methoxy cinnamaldehyde, 2-hydroxy-1-naphthaldehyde, 2-methoxy-1-naphthaldehyde, 9-anthraldehyde, 5-bromo-2-furaldehyde, 5-nitro-2-thiophene carboxaldehyde, 9-ethyl-3-carbazole carboxaldehyde, 4-stillbenecarboxaldehyde, 2-hydroxy-5-methyl-1,3-benzene dicarboxaldehyde, terephthal dicarboxaldehyde, 2-(diphenylphosphino) benzaldehyde, 1-(phenylsulfonyl)-2-pyrrolecarboxaldehyde, 1-pyrene carboxaldehyde, phenanthrene carboxaldehyde, 2-fluorenecarboxaldehyde, poly((phenyl glycidyl ether)-co-formaldehyde), poly((o-cresyl glycidyl ether)-co-formaldehyde), poly(ρ-toluenesulfonamide-co-formaldehyde), or mixtures thereof.
Dependencies are inferred from the claim text.